lec10.pdf - 17.5C Oxidation of alkyl benzenes with KMnO4...

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1 Exam 1 – Thursday, 8:45-10:15 pm Chapters 15-17 Focus on material covered in class and workshop. The first 10 questions are multiple choice and worth 5 points each, and should be answered by filling in the appropriate bubble for each question. Questions 11-17 are short answer questions with points indicated on the question. These questions should be answered in the space provided on the front and back of the answer form. 1. KMnO 4 OH - , D 2. H 3 O + The reaction begins with oxidation at the benzylic carbon and requires at least one H on the benzylic carbon. 17.5C Oxidation of alkyl benzenes with KMnO 4 2 1. KMnO 4 OH - , D 2. H 3 O + 1. KMnO 4 OH - , D 2. H 3 O + 1. KMnO 4 OH - , D 2. H 3 O + No reaction Which reaction will not occur? A. B. C. D. Both B and C X 3 4 What is the intermediate formed here? HBr (1eq)
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5 What is the intermediate formed here? HBr (1eq) What is(are) the product(s) you get in the next step? Which is the kinetic product? Which is the thermodynamic product?
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