Chapter 20 HW

Chapter 20 HW - Chemistry 52 Chapter 20 Problem Set 1...

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Chemistry 52 Chapter 20 Problem Set 1. Predict the major organic product of each of the following reactions. If no appreciable reaction is expected, write NR. NH 2 2 H N O OH O NO 2 CHO a) b) c) d) e) f) 1) PhCHO, NaCNBH 3 2) H 2 CO, NaCNBH 3 3) mCPBA 1) excess CH 3 I, NaHCO 3 2) NaOH, 1) LiAlH 4 2) H 2 O 3) HONO 1) SOCl 2 2) NH 3 3) NaOH, Br 2 1) SnCl 2 , HCl 2) HONO 3) Cu 2 O, Cu(NO 3 ) 2 1) CH 3 2 , NaOH, 2) H 2 , Pd/C 3) PhSO 2 Cl, Et 3 N
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2. Suggest reagents and conditions to selectively accomplish the following conversions. NO 2 MeO Cl O O O O NH O O N 3 H N OH 2 H N O F TN a) b) c) d) e) f) 3. Propose a reasonable mechanism for each of the following transformations.
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Chapter 20 HW - Chemistry 52 Chapter 20 Problem Set 1...

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