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Review%2010 - H Rewew l0 1" °q IR sped-re Scopy Mags...

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Unformatted text preview: . H. . Rewew l0 1" °q IR sped-re Scopy Mags SPPC'h-ome-H-y IR SPGC‘H'OSCOP)! THE ELECT R0 MAGNETIC SPECTRUM Wavelength lmetresl Radio Microwave Visible Ultraviolet X—Ray Gamma Ray 103 m?- Iu-S 106 10-3 10-10 1012 Frequency EH2] X: quflenS-l-h 2.5 Mm — \‘1 Mm oH~en expressed as y“ = 1) CM" I\ K«WWI-S wavénumher' IR: l"000 cm“ {-0 (300 cm" W \——-—l 1.5 MM 9.? wave I————§__4 I4000 wow“ in one cm W~a~> requy a "any a Campwl'cf' \QSQr Measure “TM in vs. “SK-r owi- 7. {'ranSmi-H' mac: 0 \ $0M?“ '\S (“axorbing “.9“? wk HMS wavfi‘anHn IR energy '. 5~\0 ted/mar. h0'\- enough +0 bveak bonds Mom 5“; km“ encuak +5 JtShf+ Ham 1 .z m W v '3 k 'F m: m: m. MI. 1» ‘ . V wi“ meremo vi: - s+m= sw'mg (wongbma) ‘ SM a.“ masses ex: o—H C' H 13mm“ mass cu Rome cm" ' e r'M- ‘39:: ‘ +erm300‘ “me" E ‘s‘ “3 oJcoho‘ n " ions moving 3a a mafinefic Rem expenence a» Force , F: V X3 . :‘ /' }‘1 K?“ mgr“ J M «- Jflec-kor 6““?- "°‘°"“‘/‘e “ii-h oguad Force, heavier +h|°nss occflmm-h flower (F=ma) FRAGMENTA‘HON A roohco‘ cog-Hon 'IS uns‘l'abw and will Spon+qneoufly (39.“ apex-I- %“: <:"= *' cu3- c - ca3 L, CH3 - c-cu; am emu-ran is I | mess'mg- CH; CH3 puHQd ou+ O“: a c-c bond knock OFF on! ?— CH3 4.. . Lewis 40'" Clay oc-cu3 ”"3“" CH3\ wuss-Eng M fled-ma Fragmen'l' - one. N1”; (bond is half-broke") 39+: HAG Nee-Han (—r rod E cod ), o+her has“? is (-9 CH ' o 3 0 C'H3 0 CH3 ‘ f c"'3. CH3 - {‘63 ca; CH; CH3 om, do+ec+ ion?! 99““ od- \ peak ad- Cno-l- newh'al radicals) MI! : \5 "It 3 5'7 57 4/— basc Peak= Ha} peak 09/ kighes-I- in-I-cnSH'y M’" '72. Dom-I- wart-3 abou‘l' weird peaks Caused by rearrange mom-PS, 3+6. m/z {tax} *0 593 °" )\. (in \@ .«13H3 3 / w )' @213 «It ~ '71 \ 51 r N @ 51 © 71 L03 8 OF “2.0 (For okokMSX :loH CH3- CH},- CH - CH2.- CH3 9 ‘1..-“- ®&’\H c, - H3 cut—w-cnz-c‘M at 3 a" H . @ ‘g’H CH - 3 CH ‘ ‘ ‘ 1 CH CH2: CH; (3:: HM: 'on +0 ‘03: 05 H10 M-‘g Gar alcohols 0‘ C‘QoVogQ: one carbon awauj (cl carbon) Favo:ra‘°“j weaves From 0 [CH3§ CH, "O" CHz‘CH3]+. 49 a a s l ' @H —6- CH -CH CH3 :U‘ 1 3 S'I'abilized by 1 resonance! cuzzg- cH; -¢H3 Aux/lie cleavage 4.. [em = CH - avid-CH3] l fig CH2. = CH ~ CH1 CH3 (341‘ CH=CH2 S-habfl'vzeé By reSonance For bo-Hfi U- den-vase and aflyhc c|eava¢30, c\eo.ve +0 (3%“? ‘aosi-Hve charge On We side wH-h We 1\ bond or 0 lane pairs -) Mew s+odoui22 ® by resonance. '56 = M—l? 00$: 99 HzOW '13 :: CH3- elk-QC“: ("' (Rh-d» T CH3-CH;— cud-cu; —OH O G ,I cu; '0H3'CH3 cuz‘féu t I'CS. M" = OH 6‘5\ CH; 9 q. 2.“ 7- Csz (E'thI group) vW W —9 EH3 9M 3 "-12:23 M G W/ V?) 5M"; W "Rh.= 59 here MH ‘3 7.77. I'NRIMH-y ot— M“" (U: have are 7 0:) E3: 3: e+her -\e"’ 4.. cu}.- cu- §- cl-I- cu; —, ens—cu- B-cH—cn33 | l \ ' cu; cH; ca; 6 C“; «~11: Ioz -- .. 9 CH3- (EH "' 96 CH“ “‘3 "‘ (‘43- ca - o: (ZR-CH; ' I e ‘ I CH3 CH3 CH3 CH3 M]; = ‘13 CH3- -cn-I- 0 46-1” CH3 a car?“ '3: cu ha, I (1.43 J04: CH3 ca; 9 . CH3- fiH-g -?H CH3 CH3 CH3 m]: a 87 +l [carc‘u- 9- c‘mé c143} /' CH3 CH3 You can use busi- wr He M*° wi‘Hnou-P sped-[Why where +he misfing flee-Hon came #rom; brouk one 0? “no bond: as uSucI (one side 3e+s -, o-Hner side is Q). ...
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