sc-215533.pdf - SAFETY DATA SHEET Santa Cruz Biotechnology Inc Revision date 06-Dec-2016 Version 1 1 IDENTIFICATION OF THE SUBSTANCE\/PREPARATION AND OF

sc-215533.pdf - SAFETY DATA SHEET Santa Cruz Biotechnology...

This preview shows page 1 out of 7 pages.

You've reached the end of your free preview.

Want to read all 7 pages?

Unformatted text preview: SAFETY DATA SHEET Santa Cruz Biotechnology, Inc. Revision date 06-Dec-2016 Version 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING _____________________________________________________________________________________________________________________ Product identifier Product Name Product Code Naphthalene SC-215533 Recommended use of the chemical and restrictions on use For research use only. Not intended for diagnostic or therapeutic use. Details of the supplier of the safety data sheet Emergency telephone number Santa Cruz Biotechnology, Inc. 10410 Finnell Street Dallas, TX 75220 831.457.3800 800.457.3801 [email protected] Chemtrec 1.800.424.9300 (Within USA) +1.703.527.3887 (Outside USA) 2. HAZARDS IDENTIFICATION _____________________________________________________________________________________________________________________ This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification Acute toxicity - Oral Carcinogenicity Flammable solid Category 4 Category 1B Category 2 Label elements Signal word Hazard statements Danger Harmful if swallowed May cause cancer Flammable solid Symbols/Pictograms Precautionary Statements - Prevention Precautionary Statements - Response Precautionary Statements - Storage Precautionary Statements - Disposal Santa Cruz Biotechnology, Inc. Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Keepawayf r om heat / spar ks/ openf l ames/ hotsur f aces.— No smoking Ground/bond container and receiving equipment IF exposed or concerned: Get medical advice/attention IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth In case of fire: Use CO2, dry chemical, or foam for extinction Store locked up Dispose of contents/container to an approved waste disposal plant 1/7 Revision date 06-Dec-2016 SC-215533 - Naphthalene _____________________________________________________________________________________________________________________ Hazards not otherwise classified (HNOC) Hazards not otherwise classified (HNOC) Not applicable Other Information NFPA Health hazards Flammability Stability Physical and chemical properties 2 2 2 - HMIS Health hazards Flammability Physical hazards Personal protection 2 2 2 - 3. COMPOSITION/INFORMATION ON INGREDIENTS _____________________________________________________________________________________________________________________ CAS No Molecular Weight Formula Chemical Name Naphthalene 91-20-3 128.17 C10H8 CAS No 91-20-3 Weight % >98 Oral LD50 = 490 mg/kg ( Rat ) = 1110 mg/kg ( Rat ) Dermal LD50 = 1120 mg/kg ( Rabbit ) > 20 g/kg ( Rabbit ) Inhalation LC50 > 340 mg/m3 ( Rat ) 1 h 4. FIRST AID MEASURES _____________________________________________________________________________________________________________________ First Aid Measures General advice Eye contact Skin Contact Inhalation Ingestion Self-protection of the first aider If symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. Consult a physician if necessary. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Remove to fresh air Call a physician If breathing is irregular or stopped, administer artificial respiration Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation Rinse mouth. Drink plenty of water. If symptoms persist, call a physician. Do NOT induce vomiting. Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES _____________________________________________________________________________________________________________________ Suitable Extinguishing Media Suitable Extinguishing Media Unsuitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. None. Specific hazards arising from the chemical Specific hazards arising from the chemical No information available. Santa Cruz Biotechnology, Inc. 2/7 Revision date 06-Dec-2016 SC-215533 - Naphthalene _____________________________________________________________________________________________________________________ Hazardous combustion products Carbon oxides. Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge No information available. No information available. Protective equipment and precautions for firefighters Protective equipment and precautions As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH for firefighters (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________________________________ Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Environmental precautions Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Use personal protective equipment as required. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. Take up mechanically, placing in appropriate containers for disposal. Avoid creating dust. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE _____________________________________________________________________________________________________________________ Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Store at room temperature. None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION _____________________________________________________________________________________________________________________ Control parameters Exposure Guidelines Other Information . Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Chemical Name Naphthalene 91-20-3 ACGIH TLV TWA: 10 ppm S* OSHA PEL TWA: 10 ppm TWA: 50 mg/m3 (vacated) TWA: 10 ppm (vacated) TWA: 50 mg/m3 (vacated) STEL: 15 ppm (vacated) STEL: 75 mg/m3 NIOSH IDLH IDLH: 250 ppm TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Santa Cruz Biotechnology, Inc. 3/7 Revision date 06-Dec-2016 SC-215533 - Naphthalene _____________________________________________________________________________________________________________________ Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Skin and Body Protection Respiratory protection General Hygiene Considerations Tight sealing safety goggles. Wear protective gloves and protective clothing. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. When using do not eat, drink or smoke. Wash contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES _____________________________________________________________________________________________________________________ Physical State Appearance Odor Solid No information available No information available Property Values pH Melting point/freezing point Boiling point Flash point Density Evaporation rate Upper flammability limits Lower flammability limit Vapor pressure Vapor density Specific gravity Water solubility Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Explosive properties Oxidizing properties No information available 79.5 °C 218 °C 80.0 °C CC (closed cup) 1.09 g/cm3 No information available 5.9% 0.9% 1.0 mmHg No information available No information available No information available No information available 3.4 526.0 °C No information available No information available No information available No information available 10. STABILITY AND REACTIVITY _____________________________________________________________________________________________________________________ Reactivity Chemical stability Possibility of Hazardous Reactions Hazardous polymerization Conditions to avoid Incompatible materials Hazardous Decomposition Products Not applicable Stable under recommended storage conditions. None under normal processing. No information available. Extremes of temperature and direct sunlight. Strong oxidizing agents. Carbon oxides. 11. TOXICOLOGICAL INFORMATION _____________________________________________________________________________________________________________________ Information on likely routes of exposure Santa Cruz Biotechnology, Inc. 4/7 Revision date 06-Dec-2016 SC-215533 - Naphthalene _____________________________________________________________________________________________________________________ Inhalation Eye contact Skin Contact Ingestion No data available. No data available. No data available. No data available. Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic Toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Blood, Central nervous system, Eyes, Kidney, Liver, Skin. The table below indicates whether each agency has listed any ingredient as a carcinogen. Target Organ Effects Carcinogenicity Chemical Name ACGIH IARC NTP Naphthalene A3 Group 2A Reasonably Anticipated 91-20-3 Group 2B ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans NTP (National Toxicology Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present OSHA X Numerical measures of toxicity - Product Information Unknown acute toxicity No information available The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 500 mg/kg ATEmix (inhalation-vapor) 340 mg/l 12. ECOLOGICAL INFORMATION _____________________________________________________________________________________________________________________ Ecotoxicity May cause long lasting harmful effects to aquatic life Chemical Name Algae/aquatic plants Fish Naphthalene 91-20-3 0.4: 72 h Skeletonema costatum mg/L EC50 5.74 - 6.44: 96 h Pimephales promelas mg/L LC50 flow-through 1.6: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 31.0265: 96 h Lepomis macrochirus mg/L LC50 static 1.99: 96 h Pimephales promelas mg/L LC50 static 0.91 - 2.82: 96 h Oncorhynchus mykiss mg/L LC50 static Toxicity to Microorganisms - Crustacea 2.16: 48 h Daphnia magna mg/L LC50 1.09 - 3.4: 48 h Daphnia magna mg/L EC50 Static 1.96: 48 h Daphnia magna mg/L EC50 Flow through 0% of the mixture consists of components(s) of unknown hazards to the aquatic environment. Persistence and degradability Bioaccumulation Mobility No information available. No information available. No information available. Chemical Name Naphthalene 91-20-3 Partition coefficient 3.3 13. DISPOSAL CONSIDERATIONS _____________________________________________________________________________________________________________________ Santa Cruz Biotechnology, Inc. 5/7 Revision date 06-Dec-2016 SC-215533 - Naphthalene _____________________________________________________________________________________________________________________ Disposal of wastes Contaminated packaging Other Information US EPA Waste Number California Hazardous Waste Status Disposal should be in accordance with applicable regional, national and local laws and regulations. Do not reuse container. Waste codes should be assigned by the user based on the application for which the product was used. U165 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name Naphthalene 91-20-3 California Hazardous Waste Status Toxic 14. TRANSPORT INFORMATION _____________________________________________________________________________________________________________________ DOT UN/ID no Hazard Class Packing Group Proper shipping name Description Marine pollutant Emergency Response Guide Number UN1334 4.1 III Naphthalene, crude UN1334, Naphthalene, crude, 4.1, III, Marine pollutant This product contains a chemical which is listed as a marine pollutant according to DOT 133 IMDG UN/ID no Hazard Class Subsidiary hazard class Packing Group Proper shipping name Description Special Provisions EmS-No Marine pollutant UN1334 4.1 P III Naphthalene, crude UN1334, Naphthalene, crude, 4.1 (P), III, Marine pollutant 948, 967 F-A, S-G This product contains a chemical which is listed as a marine pollutant according to IMDG/IMO IATA UN/ID no Hazard Class Packing Group Proper shipping name Description UN1334 4.1 III Naphthalene, crude UN1334, Naphthalene, crude, 4.1, III 15. REGULATORY INFORMATION _____________________________________________________________________________________________________________________ International Inventories All of the components in the product are on the following Inventory lists TSCA (United States): Canada (DSL/NDSL) Europe (EINECS/ELINCS/NLP) Australia (AICS) South Korea (KECL): China (IECSC) ENCS (Japan): Philippines (PICCS) Chemical Name Naphthalene TSCA X DSL X NDSL - EINECS X ELINCS - ENCS X IECSC X KECL X PICCS X AICS X X - Listed TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances Santa Cruz Biotechnology, Inc. 6/7 Revision date 06-Dec-2016 SC-215533 - Naphthalene _____________________________________________________________________________________________________________________ ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive hazard Yes No Yes No Yes CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Chemical Name CWA - Reportable Quantities 100 lb Naphthalene 91-20-3 CWA - Toxic Pollutants CWA - Priority Pollutants X X CWA - Hazardous Substances X US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name Naphthalene - 91-20-3 California Proposition 65 Carcinogen U.S. State Right-to-Know Regulations Chemical Name Naphthalene 91-20-3 New Jersey X Massachusetts X Pennsylvania X 16. OTHER INFORMATION _____________________________________________________________________________________________________________________ Revision note No information available Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Santa Cruz Biotechnology, Inc. 7/7 ...
View Full Document

  • Summer '19
  • Occupational safety and health, Chainsaw safety clothing, Santa Cruz Biotechnology

  • Left Quote Icon

    Student Picture

  • Left Quote Icon

    Student Picture

  • Left Quote Icon

    Student Picture