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zimmerman-quiz6-key - Quiz 6a M‘l Organic Chemistry 345...

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Unformatted text preview: Quiz 6a M‘l Organic Chemistry 345 ' Name (Please Write Clearly) Spring 2006 ' Give the products of synthesis as isolated after workup. - fin; sf 5 u 0—» 1: “a ' N\ “H Ike/Q ”is; Me _ 9 (+3 9 Q Q, _ 2) Benzyl Bromide + Na+ IN=N=NI ——» [014C HC—Ig’ U 5U’ ' ‘ ‘ warm 2 e 3) PhC—N LiAIH4, Etgo W‘w>~ NH” “if“ n of? ‘ 4) Ph fl: NH2 Br2, NaOH P L’A/HL 5) Ph’CEO ‘ PAW/5 C10 N3 A Benzene 0 l0 6) _ KOH, EtOH °H 4. irf’v‘NHz, N-I-Pr (H20) A OH - O b 7) N02 NH? __. @l Fe, HCI O 8) NH _ )KOH LiK 5f 2) Et- | O A N ,. -cbl -—P ' 9) Ph-N=C=O + Benzyl Alcohol —> 00h” N‘E o . 2‘ '10) Ph- \=o plrcfi; UH). - We2 LiAlH4, EtZO Which is more basic, Aniline or p-Nitroaniline? Aw If 6 (AnsWer). How about the basicity 11) of Ethylamine compared with Acetamide, the more basic is fit jiWMHAnswer). Now compare Aniline with Cyclohexylamine; the more basic isC o( u Jam‘lm . ' ...
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