AnswProblemSet5

AnswProblemSet5 - 2. H 2 O 3. CN excess NaOH excess I 2 1....

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1 of 3 Chemistry 2262-002 Dr. K. M. Smith PROBLEM SET 5 March 18, 2008 1) Write full and complete mechanisms for each of the following reactions, showing all electron movements with curved arrows: A B H 1. CN O O 2. HCl O H NC HOCH 2 CH 2 OH O H OH H OH H OH H OH OH H OH O H OH O B B (B ) H B OH 2 H OH O OH O H H O O H B H O O H O O + BH O O O CN NC H NC
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2 of 3 2) In the boxes below, fill in the product(s), reactants, or reagents, for the following reactions, as appropriate. If you think that no reaction will take place, insert NR in the box. O 1. (CH 3 ) 2 CuLi OH O 1. CH 3 MgBr product(s) product(s) product(s) product(s) product(s) product(s) 2. CH 3 CH 2 OH 2. H 3 O NHCH 3 O CH 3 OH OH O 1. PBr 3 /Br 2
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Unformatted text preview: 2. H 2 O 3. CN excess NaOH excess I 2 1. Br 2 , H 3 O 2. CN A) B) C) D) E) F) CH 3 O O O CH 3 OH O + CH 4 NHCH 3 O OCH 3 OH O CN O O + CHI 3 O CN 3 of 3 1. LDA/THF product(s) starting marterial(s) starting marterial(s) NH 2 CH 3 G) I) J) K) L) 2. CH 3 CH 2 Br H) 1. CN O OH CN 2. H 3. NaBH 4 /H 2 O O CH 3 NH reagents reagents reagents O O O OH OCH 3 O Br CH 3 O Br Br O O O 1. HBr 2. CH 3 OH/HCl/ heat 1. CH 3 CH 2 COCl/ AlCl 3 2. Br 2 excess, OH O CH 3 O CH 2 OH O 1. HOCH 2 CH 2 OH/ HCl 2. LiAlH 4 3. HCl/H 2 O-end-...
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This note was uploaded on 03/30/2008 for the course CHEM 2262 taught by Professor Smith during the Spring '08 term at LSU.

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AnswProblemSet5 - 2. H 2 O 3. CN excess NaOH excess I 2 1....

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