PPS 11 solutions

PPS 11 solutions - 1,4 enantiomers 2,3 enantiomers 1,2...

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C357 PPS#11 Solutions Page 1 of 1 1) Give the products of the following reactions, assign the stereochemistry of the product(s), and in the case of multiple products, tell the relationship of the products. H 3 C Br Br CH 3 H 3 C HOH 2 C Br CH 3 Br CH 3 H 3 C HOH 2 C CH 2 CH 3 CH 3 CH 2 CH 3 CH 3 CH 3 H CH 3 H 3 C H Br Br H CH 3 H 3 C H Br Br H CH 3 H 3 C H Br HOH 2 C H CH 3 H 3 C H Br HOH 2 C H H Br CH 3 Br CH 3 H H H CH 3 H 3 C Br CH 2 CH 3 HOH 2 C Br CH 3 H 3 C H CH 2 C H 3 HOH 2 C Br CH 3 H 3 C H CH 2 CH 3 HOH 2 C H CH 3 H 3 C Br CH 2 C H 3 HOH 2 C CH 2 CH 3 CH 3 OH H OH CH 3 CH 2 CH 3 H CH 2 CH 3 CH 3 H OH H CH 3 CH 2 CH 3 OH CH 3 OH H 2 /Pt H 2 /Pt H 2 /Pt HBr, HOOH H 2 SO 4 /H 2 O H 2 SO 4 /H 2 O A) B) C) D) E) F) enantiomers enantiomers enantiomers 1 2 3 4
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Unformatted text preview: 1,4 enantiomers 2,3 enantiomers 1,2 structural 3,4 structural Note: There are also diastereomers! (yes, 4 more products, not drawn due to space limitations, you should draw all!!) 1 2 3 4 1,2 diastereomers 3,4 diastereomers 1,4 structural 2,3 structural Note: There are also enantiomers (yes, 4 more products!!) (see above) Single Product ! or "...
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This note was uploaded on 03/31/2008 for the course CHEM 3570 taught by Professor Ganem, b during the Fall '06 term at Cornell.

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