04 - 5) mCPBA 6) NaOH, H 2 O OH HBr, ether OH OH w. Na + OH...

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OH OH OH OH OH OH OH OH OH OH OH OH OH O Chem 212 Alcohols and Ethers ANSWERS 1. Provide products for the following reactions. O a. b. O c. d. e. f. g. O h. i. O j. k. l. O m. n. O NaH O PhMgBr H 2 SO 4 H 2 O, HBr PBr 3 O SOCl 2 pyr TsCl, pyr Br CrO 3 H 2 SO 4 Br PCC OH Na 2 Cr 2 O 7 Me 3 SiCl Et 3 N OH 1) NaH 2) MeBr OH H 2 SO 4 O 1) Hg(O 2 CCF 3 ) 3 , propanol 2) NaBH 4 OMe o. OH p. q. O O r. s. t. u. v. Cl O y. z. CF 3 CO 2 H O Si HBr HI O mCPBA OTs mCPBA O H 1) Cl 2 , H 2 O 2) NaOH KOH, H 2 O 1) PhMgBr 2) H 3 O+ 1) LiAlH 4 2) H 3 O+ O O 1) MeMgBr 2) H 3 O+ 3) H 2 SO 4 , 4) 1,3-butadiene, heat
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Unformatted text preview: 5) mCPBA 6) NaOH, H 2 O OH HBr, ether OH OH w. Na + OH Ph x. NR + EtI OH (trans, racemic) OEt (cis, racemic) OH OH 1) mCPBA 2) NaOEt, EtOH (trans, racemic) + PhH OH OH MgBr (racemic) (racemic) and enantiomer Br and enantiomer OH + (see pg 689 McMurry) + EtBr achiral...
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This note was uploaded on 06/04/2009 for the course CHEMISTRY CHEM 2020 taught by Professor Mr.pottvine during the Fall '06 term at Indian Institute of Technology, Chennai.

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