C357_Final_Exam_A_2004_comp - Cornell University Chemistry...

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Cornell University Chemistry 357 Summer 2004 Final Examination July 02, 2004 Instructions: Read all questions completely before answering. If the question is still unclear, be sure to ask for clarification. You may find it helpful to first answer those questions that you find easier and then return to those you find more difficult. Good Luck!!! Possible Problem Score 1 20 3 25 4 5 6 7 8 9 10 30 16 20 25 25 16 2 25 16 11 12 14 13 12 30 30 30 TOTAL 400 15 30 30 16 17 30 Name:_____________________________________________ Signature:__________________________________________
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Page 1 of 14 1) (20) Provide IUPAC names for each of the following structures and write your answer on the line to the right of the structure. Be sure to include any appropriate stereochemical designations. a) b) c) d) e) H 3 C H H H H 3 C CH 3 H CH 3 Br CH 3 Br H CH 3 H H CH 3 H 3 C H
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Page 2 of 14 2) (25) The following bimolecular reaction can produce 5 products with the chirality shown, in addition to relationships with the other products. Draw the correct products in the boxes shown. OH Br H H H NaOH, H 2 O Chiral Chiral Achiral Achiral Achiral Product A Product B Product C Product D Product E R e l a t i o n s h i p s A and B are structural isomers B and D are structural isomers B and E are structural isomers A and E are structural isomers A and D are structural isomers D and E are diastereomers C has no relationship to A, B, D, or E
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Page 3 of 14 3) (25) In the molecule whose structure is given below, encircle and identify the following: a. a sigma bond b. a pi bond
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This note was uploaded on 04/01/2008 for the course CHEM 3570 taught by Professor Ganem, b during the Summer '06 term at Cornell University (Engineering School).

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C357_Final_Exam_A_2004_comp - Cornell University Chemistry...

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