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C357_Exam_2_2004_comp

C357_Exam_2_2004_comp - Cornell University Chemistry 357...

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Cornell University Chemistry 357 Summer 2004 Examination II June 25, 2004 Instructions: Read all questions completely before answering. If the question is still unclear, be sure to ask for clarification. You may find it helpful to first answer those questions that you find easier and then return to those you find more difficult. Good Luck!!! Possible Problem Score 1 13 3 10 4 5 6 7 8 9 10 20 20 15 20 20 18 2 21 20 11 12 11 12 TOTAL 100 Name:_____________________________________________ Signature:__________________________________________
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Page 1 of 9 1) ( 13 pts) Provide an IUPAC name for each of the structures shown below and write your answer on the line to the right of the structure. Or, when given a name, draw the appropriate structure on the line. Be sure to include any required stereochemical designations. A) Br B) C) D) E)
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Page 2 of 9 2) ( 21 pts) There is an alkene, call it Compound X , with the molecular formula C 9 H 18 , that reacts to produce the number of carbon-based major compounds shown below in each reaction. The products are also stereochemically described. Based upon the reactions and product distributions, draw the structure of Compound X and the structures of all of the products. All drawings must be drawn so that their stereochemistry, if any, is unambiguous. Ambiguous answers will graded as incorrect.
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