Chemistry 1A - Fall 2003 - Head-Gordon - Midterm 3

Chemistry 1A - Fall 2003 - Head-Gordon - Midterm 3 - Him...

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Unformatted text preview: Him jimfl [flag SEEI'IDH I: EQUIIJBEILTM Furquastiuna l- 1| muidflthu: followingthraa matinmnllfiflli. 1 El '5? '- ESUI‘MJ‘H lflzig}+25{=} K=II.III 511'»qu 3% H.125 II“ n.5{31+n=m-- scum I'll-225 IIH'=-2mu III-15mm] “Clam” 25¢):th d “ ' 1.] WhthfiuuquifibfimnmnmtfmanflxmflflzjflundEflggasllznnllll? 3 «H $15.: 13$: "’5' 30-: *3! W 5.ququ E30111 T 52:] l! " EH} - 1 @J x m" - flirifll H __ 1' I; £191: ”53"]? I- 113“" ' ' : 113:5 EEE‘H '32 vim; - itthawhuufthaaquilibrium what farm l il'nIaqniHbI-imnflu flnkmnlainafllifi arm 503, 0.qu film (3:, Mid ll._l;|'l-ESiIIfiIr Ifier a tamperlllm: change. =d1augehuammiffln vllunaffl furnnlifinundl-nMHJSZI mmflmpcmhme. - ammmmm. Clmmminprmm. _ 1 ~'.-‘-. [Aninminwlm 13; - magma. 4.} Wuhiauuitahleuprmimfmthcmmfimmnfimfmthcfumfim ufmfimnflu clunmll? A} Hm} I P {513:} E"; E} Pat-3:11” DI: r PIES) 1"- I PIE-1:}! {SW} fiflflf Ptflzl Hmhjngmba said will: than mumgim- 5.] What in: AW farm-Him III? 333” @131 u II] 1.7: “flu D} 51:] E] Insu Pugh}! Name 15m“ NEH“: 6.} Wchismhmmmuffl]: lE-ifli'h'l: mthnipiaauffmmnflan afwmflfll. and 50:? 303 _' -'3ii'!§.§ wt} fig]: 153/1 Bill 1 511-; mfltflzfiflasmsu; git-.0 — S'fli'il SD! 5C": 5U: 01 Tflfiflnhmwmflinfimuffifi‘fmmflmIMEflfiK? 'mi' 'h-{l Egg} fig“: EH Buy-n ESE“ flay-:11] Dins'so E} as'afl 5.] 'i'fhatcunyuusaylbnm ralcfimlatlfiflfl? Ami/[.1 is “albumin. It is m 1'. is ml Was. It is at equilibrium. [1mm hm:— 9.) Thuummmlalmfur luff.“ lfl‘furrcantiun lwuuldpusfltrough whichpiirufpuintaifill inbuth Wmmmahm}? inii= Ffi—H-{L T Jig +1: n-Whiuhuflhafuiluwingstflrtinznmfiflm waniditbtimpmsiblefhrmuilibriummb: ‘ u-fiJrructiunI]? SEMI]- "' mixmuffiflzmfiuisl. Infill}- E} Amixmrenfflmiliflndfihifl- Pinata) and 5 {a}- @quilibrimn can ha amine-:1 fium any affirm starting umrditiuns- Name 113,913 I MEL: 11.] Whichmeumwhmaddiugfi{a}mflteequflihfium deanihedhyrfleflmlfllmdllfl' A] Adlemehltheprflemeufflflgmj- B] Adureueihemweufsflzig}. C} Anhminthenhenfmeeqniflhrhnnemtam. mmmflwtfltalpreflureefdlesyatem. themehtheequilihrim. J. .__ ,_-..-. ..._..‘.._. " .. I? :1..._... ':_I' 5'6 ‘_-:.JI:1'" "hf-711:3." -_I--r.-:al;'.._:.. '_ '-'e|"1..l!._'|.: EFT-Edit":- -. -' 4._;.q=_._—-.,::__ . ._ __:_:_. . . _ _ I - - I. 1: .-_: _ _. . nut:- 11} Furthemfiun Am + this) —+ mm + 2m infill: hfi' - M It! at 25'C. the eqtdhhrimn mixture it} will consist almuet exclusively MA and I}. will enlist almost etc-[infinity an and I. will amidst almuat exclusively Inf}: and I- } will Wt trf significant ammmts DEA. D, I, and}; E} III: Immifiun peedieublemlyif‘unehmws‘l' mdhfl'andhfl'. I1} The equih‘hrium militant far the reaetimi helm: at 251: is 4.3 it ll)". Eeleullte the equilihi'itlm enneentretion [null] at E]: {3} if the initial cement-Minn afIC] {a} is 1-33 melfL. Them iii no I: WEI: initially present. m‘im 3 x1 turf”: 1 = : HhiiflJHJIflIE} 4 iI-‘TT‘ 3133'le 1|- 4"- +fl 3": white ”Eu-amofl ‘ I??? : 5-51m" _ 1‘ ‘3 mun-it i“ "Silt“? 11'} um" E] 3.43 14.] Whichut'thefefluwingequflihria, wiliehifituflieleflinrtapmtfltuefieermeinwlm? .Hm+cmg}fi IHCIILE} . fl-tflamuzsmmmim {:“m W” 'NriE‘J-FEHfiEir-INI-laie} ,nj' 4mg)” 01.15;. H 2 Fania] E] IHIIEJ H HHS} "' HE} Him: Em“ EEEE 15.] [Sunshin- the falluwing reaction It equilibrium: 2mg] H zmjwmfl fiH' mm H Huwmniheyiald ufflfliflbcnmimifld? }athigh.tcmpmamreandhighpmfim athightfinpflrammdluwprm utiuwtmnpflahnemdlnwpmc atlawtempfimfltandhighprmm E} inthaprmufmlidcnrbon 16.] Whiuhiamfbrwmmfimifflutmpunmismimd? j Chmmt mfiun: rm: pluducts. B Chemical minus flaw: mm“. M: Chung: in untamed. Equilibrium unnatural! inm an: ufthnc. Furth: ihlluwing threw: quutiuns. wider 1h: aquilibtium P115111. {5) H lit-r;t {lg} + SD": (an) m¢hulK¢-].EIIUE uflfifl ”:1" 1?.) What' u. thu cmflm uflead inns in wait: [hfl whm solid PbE-Dq is plant? 1.51m“ 31“!" 1 Lu D] Halli" E5115 IE.) What hfllzmmhaliunuiludimsfluflmflfll MNaSD.{K..,—-1fl'] when miid Phfifliil ' r. H: 1 —l‘ @113: Ah {EMHJJI 1 E 11.31:] C] [.0 In 1.11m“ E} 21.5 ”Iii-Jim is NSF fur the disamluflm fififld mlfltu at 2'93 K. [kflmnl]? B) 43 M :1 5.9 “a = rfirlulri 31$:ng : -2111;er n win} ""1"“ ) I'll: "II-LI". itetgtezet are ___+ SECTIDN 2: PHASES DF MATTER Fer the feline-m3 queetient manager the phase diagram t'et water helew. TI T2 T3 T 10.} Atwhiehptrintttregae. liquidated mlidallinequilihrium‘? A] {T}: PI} .PI} LEI} D} HUI} E} {111131 1].} Amwleermpendnte: A} Chestnut pleasure B} Equilibrium 5 11' . Cendenaetien } ”wine 11.} Alenatheeunre :etttejhihg the peintsffl. F1}end[T3, P3}: Eelid. liquid and gee an: all in equilibrium. ' Int-Handgun: inequilihrimn. The trepe: preeetn'e ie eenetem. D} 'I'hcmmb: mndmsedateny plum. E} (Myth: mlidphm is eheenred. 13.} At flltptrim [T1, P3} the sub-stem: is: - tneqeilihriumhetwemliqttid nudges. IBM liquid. C} A get. D} A eupemtitinl field. E]: A eelid. 23.) Which is I. start: filmtiun (marl: all flint apply}? film: humus. C} nmut if “(F1 t: ,31 ' m 4|]th .4 ,_ r 3; 4.61111: '3'; ‘1‘ 3| .1 Aha: nfhnt ml is planned in wattr in. an insulated maintain! the two are lllmlmd tn mach thmmnl aqm‘lihrium. thn] .13 lag uf maul at lflfl'C is placed in ll] 1:; at“ warn, the taupcramm 6m misc: fmm 1'0": tn 2.51:. What in the maifit: heat capacity fifth: mutal {Jig K]? .5 mud-11 C Lil-T T m CfiT B] I Hal.- E main g : M:z'“fl"1fi“5k) g; 2:25 ”"14:- fi meta It 1?— 32.) “withislhahutnttimtrfurthebuiljng paintufbenzenefi‘fij git-tn mntfifl‘nfupnriufiun it'jl Wmdandflflwapuflmfimt itWMnulK? _ A]: 25 335:“ : _If1_l-l_ 4: fi‘t k. T )1: ... “4" __ glhffm-l E} 5 T M~ M‘f’njflfm I. III in 33.1 Whichiathltfimtstepinataalisfiuaxpufimentmdcmniuthammpythmaafmachemiflli minim? 3-4.] The value afflH‘ far 1h: fulluwing reaclinn it. 435] It]. 1 Alia} + 301(3) —* ”sill-Jam Wilt it .M-l' fur tht ftrrmalitm nl' Til} g affilzfltlfin} {kl}? 9.] 4.511101 1 1 {La-5| Hr magmas 1"; a], "P “mt.“ -. (fijlfl 'ID'I-"Iba '3 m1 mull; E} +3351 131111111111. if “(F1 If: .31 ' 1:11 4111111: .4 ._ r 3; 4.1111111. '3'; ‘1‘ 3| .‘1 Aha: nfhnt ml is Find in water in. an insulated amthMrmd the 111111 an: aim ‘11: man]: 111111111111 aquilihrium. thn! .13 lag 1:1f maul at lflfl'C is place-1i 1'11 1.131 11:; 1:11“ water, the taupcramm $111.11: mina- fmm 1'0": tn 2.55:. What in the maific heat capacity fifth: 1111:1131!sz K]? 5 B] I5 mm..fl1CflT : mH,LCfiT ' 1G 1: 1“!“ El' c3112: [- —; M:E I'ffl ____.[!‘['1:) [1 25 n... 6—— $31115 111111 1.1111“ 1.1-] 32.] whichisllubaa‘t nflimtrfnrthebailjng painlufbenzenafi‘flj gimm mlthfl‘nfflpnriufiun 111 3| Wmdandflflwapuflmfim isWJIleT _ 11 AH .1125 .155.“ : -—— 15 3’41‘51 1:. T )1: “4" __ gllfiffm-l E} 5 T M“ 1-11.11. '12 I’m 1 all - 33.1 WhichislhefimHepinumalnfiuupuflmemmddnmintthammpymfmachamiflli rennin? A} MmmingfiH‘ :um'inghnwth: Eva-inn withflmwmm mmmcmm Mudfmchmjnnl rem-minus. 34.] The value afflH‘ far flu: fulluwing Inclined ii 435] 11:]. 1 11.11:} + 30:11.3} —~ lfihflalfl What is 1111' 11111111: fwmaliun 11115.11 9, ufhlzflfin} 111111 9.11.1.511111’ "ti-5| 111—1211 111115 "‘57 fl1| :- 1"”1 PM" 1.1:: -, E: .34ng Hal-Elba '1? 1-1-1 fill-['3 E] +3351 Name :1; Egg Hflflg: 35. ll\1I."hir:h aflhefhiinwiughua nun-mum fiHf'? {l} . GIMME] ’5‘} Hats} [1} Fm E} many 36.]: Which uni: uni": fullawing prawns-I is mdnlhu-min? A} main} + {11123} —- iflaflm} 13} Hams?! — Hamil} c1143} + 201$} —. can} + Iflflfl mats} - Hzflfl] mm} + Ffiflaifil —* Mathis] + EFHIII} 31"-] Which is In: far The foilnwing mam“ undar standaltl :undiliam? Czflgtsl-vCfidgHHfl} Mf=gH=TaS m- ,,_ m um 115* is 1mm. m”.- -‘1” T I spuntanmus atllltemperamms 7h} =- mmlyathightampemmm m {734" htflln fl“? spmtanm uniyltlflwlempfimnt 9F D} nulmnmms ntalltampmmres flmhcdelarminad 33.] Him the fulluwing CflmflamflwmtflfhlflinkflnuIMWhm llJSgufEflgmmtaacmrdingmfh: aquarium: HEB}; 1"“! h: :.—EP_II Eflzmi‘FCHEi-FSDJCIEIEJ - H.313 i W A} 100.5 5.1-1 ; '{n’iwm 1 B} aimxlfl’ 5; 3.5 @115 [Infinimt dam are given. Nmne T” IE: EIEHL‘E 39.} We. have mummy Em in 1mm: 11m. hut in given nfl'iu the :mnbuatiml nfhydmgm gun. whurmhmmhmblammM? H: +03 —=r I J, H“: ‘ JEmEfiuflmml H,“ M c~ wr-H - amflngH—Hbundimdfl-Dhmds. armingD-Hbandl. JCunfimfiunuf'fluwafltfinmad. an.) meaunyabuutflwmfimifflmnfinufthafl=13 duuhltbundstrengmtnflmC-C ainglebundmgfllialmthnnm? . ' (f C _ .f N... » .2 . fl . (:1 C L‘ C I '1 i I + H —=~ || i- “a E r: C a E q... C {fl “H. I: f ”A: wtldmut 19-45 5; LL SWIM L ""I hamfinnilnxufllmfia 9" r mimiamdufllmflin. Themifimiupuntmm D}Th=emhalpychmgaiuhuutm. ”flu! m1 Mm, +1.“ 11:11:: Lufla. E brattn #lwv-dq w Lam f: r. (-2“: mt:- ...
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