Li-Ion Polymer Battery_SDS.pdf - Safety Data Sheet...

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Unformatted text preview: Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 1. Identification (a) Product identifier Product name: Lithium‐ion Polymer Battery (b) Other means of identification Product description: Model: 944643‐2100mAh Nominal Voltage: 3.8V Ampere‐hour: 2.1Ah Typical Capacity: 2100mAh Weight: 34.0g Dimension: 46.0mm×46.0mm×9.75mm (L×W×T) (c) Recommended use of the chemical and restrictions on use Recommended use: Restriction on use: LITHIUM ION BATTERIES. No information available. (d) Details of the supplier of the product Company name(China) Address: E‐mail: Telephone: SPRINGPOWER TECHOLOGY SHENZHEN CO., LTD. Chaoshun Industrial Zone, Renmin Road, Fumin, Guanlan, Baoan, Shenzhen, Guangdong, China [email protected] +86‐755‐6186 2699 ‐887 (e) Emergency phone number +86‐755‐6186 2699 ‐887 2. Hazard(s) identification (a) Classification of the chemical This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). This product is an article which is a sealed battery and as such does not require an MSDS per the OSHA hazard communication standard unless ruptured. The hazards indicated are for a ruptured battery. Acute toxicity ‐ Oral Category 4 Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Carcinogenicity Category 1A Specific target organ toxicity (repeated exposure) Category 1 (b) GHS Label elements, including precautionary statements Emergency Overview Signal word Danger Hazard Statements Harmful if swallowed Causes severe skin burns and eye damage Causes serious eye damage May cause cancer -- Page 1 / 12 -- Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 Causes damage to organs through prolonged or repeated exposure This product is an article which contains a chemical substance. Safety information is given for exposure to the article as sold. Intended use of the product should not result in exposure to the chemical substance This is a battery. In case of rupture: the above hazards exist. Precautionary Statements – Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Precautionary Statements – Response Specific measures (see .? on this label) Immediately call a POISON CENTER or doctor/physician Specific treatment (see supplemental first aid instructions on this label) Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Skin Call a POISON CENTER or doctor/physician if you feel unwell Wash contaminated clothing before reuse IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower If skin irritation or rash occurs: Get medical advice/attention Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician. if you feel unwell, Rinse mouth. Don’t induce vomiting Precautionary Statements – Storage: Store locked up Precautionary Statements – Disposal: Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC): Not applicable (c) Other information Very toxic to aquatic life with long lasting effects; -- Page 2 / 12 -- Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (d) Interactions with Other Chemicals No information available. 3. Composition/information on ingredients (a) Mixtures information Chemical name CAS No. Concentration% Lithium Cobalt Oxide (CoLiO2) Graphite powder Phosphate(1‐), hexafluoro‐, lithium Polyethylene Copper Nickel Polyvinylidene fluoride Polypropylene Aluminum foil Silicon Epoxy Resin PVC Gold Tin 12190‐79‐3 7782‐42‐5 21324‐40‐3 9002‐88‐4 7440‐50‐8 7440‐02‐0 24937‐79‐9 9003‐07‐0 7429‐90‐5 7440‐21‐3 38891‐59‐7 9002‐86‐2 7440‐57‐5 7440‐31‐5 36.80 18.20 10.50 1.62 8.10 1.34 3.26 2.57 9.44 2.50 1.64 3.02 0.70 0.31 4. First‐aid measures (a) Description of first aid measures General Advice Eye contact: Skin contact: Inhalation: Ingestion: Self‐protection of the first aider: First aid is upon rupture of sealed battery. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Seek immediate medical attention/advice. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required. May cause an allergic skin reaction. Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately. Do not use mouth‐to‐mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one‐way valve or other proper respiratory medical device. If breathing is difficult, (trained personnel should) give oxygen. Delayed pulmonary edema may occur. Get medical attention immediately if symptoms occur. Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth‐to‐mouth resuscitation. Use personal protective equipment as required. Wear personal protective clothing (see section 8). (b) Most important symptoms/effects, acute and delayed -- Page 3 / 12 -- Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 Most important Itching, Coughing and/ or wheezing. Burning sensation. symptoms and effects: (c) Indication of any immediate medical attention and special treatment needed Notes to Physician Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. 5. Fire‐fighting measures (a) Extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Use foam, dry powder or dry sand, CO2 as appropriate. No information available. (b) Special hazards arising from the chemical Under fire conditions, batteries may burst and release hazardous decomposition products when exposed to a fire situation. This could result in the release of flammable or corrosive materials. Hazardous combustion products: CO, CO2, Metal oxides, Irritating fumes (c) Special protective equipment and precautions for fire‐fighters Firefighters must wear fire resistant protective equipment and appropriate breathing apparatus. The staff must equip with filtermask (full mask) or isolated breathing apparatus. The staff must wear the clothes which can defense the fire and the toxic gas. Put out the fire in the upwind direction. Remove the container to the open space as soon as possible. Spray water on the containers in the fireplace to keep them cool until finish extinguishment. 6. Accidental release measures (a) Personal precautions, protective equipment and emergency procedures Personal Precautions Other Information In case of rupture. Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Refer to protective measures listed in Sections 7 and 8. (b) Environmental Precautions Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains. (c) Methods and materials for containment and cleaning up Methods for Containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers. -- Page 4 / 12 -- Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 7. Handling and storage (a) Precautions for safe handling Handling In case of rupture. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Use personal protection equipment. (b) Conditions for safe storage, including any incompatibilities Storage Incompatible Products Keep containers tightly closed in a dry, cool and well‐ventilated place. Protect from moisture. Keep out of the reach of children. Store away from other materials. Acids. Bases. Oxidizing agent. 8. Exposure controls/personal protection (a) Control parameters Exposure Guidelines Chemical Name Lithium Cobalt Oxide (CoLiO2) 12190‐79‐3 Graphite powder 7782‐42‐5 ACGIH TLV OSHA PEL NIOSH IDLH TWA: 0.02 mg/m³ TWA: 2 mg/m3 respirable fraction all forms except graphite fibers Phosphate(1‐), hexafluoro‐, lithium 21324‐40‐3 TWA: 2.5 mg/m3 F Nickel 7440‐02‐0 Copper 7440‐50‐8 TWA: 1.5 mg/m3 Aluminum foil 7429‐90‐5 PVC (Chloroethylene, polymer) 9002‐86‐2 TWA: 0.2 mg/m3 fume TWA: 1 mg/m3 Cu dust and mist TWA: 1 mg/m3 respirable fraction TWA: 1 mg/m³ respirable fraction IDLH: 1250 mg/m3 TWA: 15 mg/m3 total dust TWA: 2.5 mg/m3 respirable synthetic dust TWA: 5 mg/m3 respirable fraction synthetic (vacated) TWA: 2.5 mg/m3 respirable dust natural (vacated) TWA: 10 mg/m3 total dust synthetic (vacated) TWA: 5 mg/m3 respirable fraction synthetic TWA: 15 mppcf natural TWA: 2.5 mg/m3 F TWA: 2.5 mg/m3 dust (vacated) TWA: 2.5 mg/m3 TWA: 1 mg/m3 IDLH: 10 mg/m3 (vacated) TWA: 1 mg/m3 TWA: 0.015 mg/m3 IDLH: 100 mg/m3 dust, fume TWA: 0.1 mg/m3 fume and mist TWA: 1 mg/m3 dust and mist (vacated) TWA: 0.1 mg/m3 Cu TWA: 1 mg/m3 dust and mist TWA: 0.1 mg/m3 fume dust, fume, mist TWA: 10 mg/m3 total dust TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable TWA: 5 mg/m3 respirable dust fraction (vacated) TWA: 15 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction (vacated) TWA: 5 mg/m3 Al Aluminum ‐ ACGIH TLV: American Conference of Governmental Industrial Hygienists ‐ Threshold Limit Value -- Page 5 / 12 -- Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 OSHA PEL: Occupational Safety and Health Administration ‐ Permissible Exposure Limits Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL‐CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control parameters (b) Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems (c) Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures None required for consumer use. If there is a risk of contact:. Tight sealing safety goggles. Face protection shield. None required for consumer use. If there is a risk of contact:. Wear protective gloves and protective clothing. No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. For environmental protection, remove and wash all contaminated protective equipment before re‐use. 9. Physical and chemical properties (a)Appearance (b) Odor (c) Odor threshold (d) pH (e) Melting point/freezing point (f) Initial boiling point and boiling range (g) Flash point (h) Evaporation rate (i) Flammability (j) Upper/lower flammability or explosive limits (k) Vapor pressure (l) Vapor density (m) Relative density (n) Solubility(ies) (o) Partition coefficient: n‐octanol/water (p) Auto‐ignition temperature (q) Decomposition temperature solid Odorless Not available. Not available. Not available. Not available. Not applicable. Not applicable. Non flammable. Not available. Not applicable. Not available. Not available. Insoluble in water. Not available. Not available. Not available. -- Page 6 / 12 -- Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 (r) Viscosity Not available. 10. Stability and reactivity (a) Reactivity Stable under recommended storage and handling conditions. (b) Chemical stability Stable under recommended storage conditions. (c) Possibility of hazardous reactions None under normal processing. (d) Conditions to avoid Exposure to air or moisture over prolonged periods. (e) Incompatible materials Strong oxidizer, strong acid. (f) Hazardous decomposition products Carbon oxides. 11. Toxicological information (a) Information on the likely routes of exposure Product Information Inhalation: Ingestion: Product does not present an acute toxicity hazard based on known or supplied information. In case of rupture: Specific test data for the substance or mixture is not available. Corrosive by inhalation. (based on components). Inhalation of corrosive fumes/gases may cause coughing, choking, headache, dizziness, and weakness for several hours. Pulmonary edema may occur with tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs. Pulmonary edema can be fatal. May cause irritation of respiratory tract. Specific test data for the substance or mixture is not available. Causes burns. (based on components). Ingestion causes burns of the upper digestive and respiratory tracts. May cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the mouth. Swelling of the throat may cause shortness of breath and choking. May cause lung damage if swallowed. May be fatal if swallowed and enters airways. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May be harmful if swallowed. -- Page 7 / 12 -- Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Skin contact: Eye contact: Component Information Chemical Name Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 Specific test data for the substance or mixture is not available. Corrosive. (based on components). Causes burns. May be absorbed through the skin in harmful amounts. Harmful in contact with skin. Specific test data for the substance or mixture is not available. Causes burns. (based on components). Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage. May cause irreversible damage to eyes. Graphite powder 7782‐42‐5 Nickel 7440‐02‐0 Aluminum foil 7429‐90‐5 Copper 7440‐50‐8 Oral LD50 Dermal LD50 Inhalation LC50 > 10000 mg/kg ( Rat ) > 9000 mg/kg ( Rat ) > 15900 mg/kg bw(rat) > 0.888 mg/L/4 h(rat) > 2500 mg/kg bw(rat) > 2000 mg/kg bw(rat) =1.03 mg/L/4 h(rat) (b) Information on toxicological characteristics Symptoms Erythema (skin redness). Burning. May cause blindness. Coughing and/ or wheezing. Itching. Rashes. Hives. (C) Delayed and immediate effects as well as chronic effects from short and long‐term exposure Sensitization Mutagenic Effects Carcinogenicity Chemical Name ACGIH Lithium Cobalt Oxide (CoLiO2) 12190‐79‐3 Nickel 7440‐02‐0 A3 Group 2B X Group 2B Reasonably Anticipated X No information available. No information available. The table below indicates whether each agency has listed any ingredient as a carcinogen. IARC NTP OSHA ACGIH (American Conference of Governmental Industrial Hygienists) A3 ‐ Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2B ‐ Possibly Carcinogenic to Humans NTP (National Toxicology Program) Reasonably Anticipated ‐ Reasonably Anticipated to be a Human Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X ‐ Present Reproductive Toxicity No information available STOT ‐ single exposure No information available STOT ‐ repeated exposure Causes damage to organs through prolonged or repeated exposure. Based on classification criteria from the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200), this product has been determined to cause -- Page 8 / 12 -- Safety Data Sheet According to HCS-2012 APPENDIX D TO §1910.1200 Version: 1.0/EN Product name: Lithium-ion Polymer Battery Chronic Toxicity Target Organ Effects Aspiration Hazard Revision date: 21-Dec-2016 Printing date: 21-Dec-2016 systemic target organ toxicity from chronic or repeated exposure. (STOT RE). Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Contains a known or suspected carcinogen. Avoid repeated exposure. Prolonged exposure may cause chronic effects. May cause adverse liver effects. Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Blood. Central Nervous System (CNS). Central Vascular System (CVS). Kidney. Liver. Lungs. No information available. 12. Ecological information (a) Ecotoxicity Very toxic to aquatic life with long lasting effects. Chemical Name Toxicity to Algae Toxicity to Fish Nickel 7440‐02‐0 Copper 7440‐50‐8 72h EC50: = 0.18 mg/L (Pseudokirchneriella subcapitata) 96h EC50: 0.174 ‐ 0.311 mg/L (Pseudokirchneriella subcapitata) 96h EC50: 0.031 ‐ 0.054 mg/L (Pseudokirchneriella subcapitata) 72h EC50: 0.0426 ‐ 0.0535 mg/L (Pseudokirchneriella subcapitata) 96h LC50: > 100 mg/L (Brachydanio rerio) 96h LC50: = 1.3 mg/L (Cyprinus carpio) 96h LC50: = 10.4 mg/L (Cyprinus carpio) 96h LC50: 0.0068 ‐ 0.0156 mg/L (Pimephales promelas) 96h LC50: = 0.112 mg/L (Poecilia reticulata) 96h LC50: = 0.3 mg/L (Cyprinus carpio) 96h LC50: = 0.8 mg/L (Cyprinus carpio) 96h LC50: = 1.25 mg/L (Lepomis macrochirus) 96h LC50: = 0.052 mg/L (Oncorhynchus mykiss) 96h LC50: = 0.2 mg/L (Pimephales promelas) 96h LC50: < 0.3 mg/L (Pimephales promelas) (b) Per...
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