Chem2311-Chapter11Problems

Chem2311-Chapter11Problems - C h e m is tr y 2 3 1 1 H o m...

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Unformatted text preview: C h e m is tr y 2 3 1 1 H o m e w o r k P r o b le m s - C h a p te r 1 1 
 1.
What
is
the
major
organic
product
obtained
from
the
following
reaction?
 a.
1
 b.
2
 c.
3
 d.
4
 2.
What
is
the
major
organic
product
obtained
from
the
following
sequence
of
 reactions?
 a.
1
 b.
2
 c.
3
 d.
4
 3.
Which
of
the
following
are
ethers?
 a.
only
1
and
2
 b.
only
1
and
4
 c.
only
1,
2
and
3
 d.
1,
2,
3
and
4
 4.
Which
of
the
following
has
the
highest
boiling
point?
 a.
pentane
 b.
methyl
propyl
ether
 c.
diethyl
ether
 d.
1‐butanol
 
 
 5.
What
is
the
IUPAC
name
of
the
following
compound?
 a.
(E)‐5‐methyl‐2‐hexen‐5‐ol
 b.
(Z)‐5‐methyl‐2‐hexen‐5‐ol
 c.
(E)‐2‐methyl‐4‐hexen‐2‐ol
 d.
(Z)‐2‐methyl‐4‐hexen‐2‐ol
 Section
II.
Predict
the
structures
of
A‐G
in
the
reaction
sequences
given
below.
 OH PBr3 A CH3 CH3 CH3CO3H B Br2 H2O NaOH C H2O D Br KOtBu E CH3CO3H H2O F H2SO4 G Section
III.
Devise
a
stepwise
mechanism
for
the
following
reaction.
 O Cl CH3 CH3CH2O O H3C O CH3 Cl Section
 IV.
 Starting
 with
 ethane,
 and
 using
 any
 other
 needed
 reagents,
 outline
 a
 synthesis
of
ethyl
isopropyl
ether.
 O ...
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