Lecture_VI_Evening

Lecture_VI_Evening - Hoaf'CuLAp. 57‘ okmmu PM?...

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Molecular Orbital Description of 1,3,5-Haxatriana 333333 = 033333 — 333333332333 “15— — 333333 333% w— 333333 332 + 333333 33 a x 3-3333 possible alignmant molecular orbitals energy levels of orbitals anorgy A + ! 1 'r I 1* ground state excited state Tansoaranoioa to aoormpany ORGANIC CHEHISTH'I' b'r Pau‘f: ‘f'urHaI'E BH—IIEE- 3‘} 1555 by Fronl-CEI-HEIII. Inc. T-Ta Woodward-Hoffmann Rules for Electresyslis Reactions TABLE 29.1 Woodwarda-Hsffmsnn ies for Eiectrocyclic Reactions Number of Allowed Mode Cnnfigsted 1T Bonds Reaction Conditions of Ring Closure Even number Thermal Conrntatery Phntscmemical msrstatnry Odd number Thermal - Disrntatory Phe’mchemieal Conrstatnry d iSrG’LE’EGW ring slssure HDMD is symmetric snnrntatcury ring eissure HUME} is asymmetric Transpamnnes ‘.:I an}: 'n-Irji’m'i.I DFIEANIC CHEMISTRY by PEP—IL! Yc-I'HEII'IIG EI'IJ'VT-fl L 199';- by Premise-Hail. |.".:. - — H.y.ygy..u....u..J u. ...-—- . -.—--_-.—--.- —-. --.. —.—-—-.r—--—J --.-.-- r.----.--1-.-.-.-. TABLE 20.2 Substituents Stereachenfistry in the Reactaflt Mode 0f Ring fluaure in the Product Point in opposite deECflflILS Disrntatnry Cris Comntatorjr trans Point in the same direction Disrutatnry’ _ trans Conrotatory cis d isrotam r3; ring ciosure ——h- HBC CH3 H H (:1er ,E- d i methyi-l ,3—cyciui‘lexadiene d i smtamry ring CID-ELITE —-——l-- H CH3 1-13C H [2542.621—Dct triene trans-Sfi-dimethyl-l,3—cycmhexadiene can magic: I}: ring closure 1W ‘1?— Hat CH3 H H :2E.42.EZ]-actatriene Q's-5,E-dimeihyI-l,3flycluhexadiene Transierenciflfi m amr :1pany UHGIMIC CHEIIISTH'I' by Paw: '“eranrs Emica : HE'S-5 by F'run'.iI:I:-H.I||. Inc.- 2mm 6P2?!ng _, ., a" u '" Myszn'mrrnfl \r” cm, was? new TM“ chmaanr/Vt! ’. dryer”; (E; G Enfgfla cm tar-tr” Farm-s. H ‘u' H IIL"‘"lr‘ “a. 'L 1'3}th l 4.:- S P I H? H HYBIIPI'EHTHIH In]!!! 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This note was uploaded on 06/25/2009 for the course CHEM 01:160:308 taught by Professor Bokiess during the Spring '09 term at Rutgers.

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Lecture_VI_Evening - Hoaf'CuLAp. 57‘ okmmu PM?...

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