Quiz_III_Key - NAME ID K V Chem308,$urnmer2008 Quiz 3...

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Unformatted text preview: NAME ID K V Chem308,$urnmer2008 Quiz 3 sections H1 1. (2 pts.) Draw the structure of the major organic product. \ O CHSOH N C \Jk Q ‘-’ \/K (—l 19‘ 2. (3 pts.) Draw the structure 01 the two organic compounds that will produce the alkene shown below, when mixed together in an inert solvent, such as diethyl ether. 0 u I 'thlether . -)l\ + >m—9fiq ..;_*__,.. — 0 >1“ (7,938) mn\\3 obi £956“ch revoke: 3. (2 pts.) Draw a Fischer proiection showing the onen chain form of the carbohydrate that is drawn as a Hawonh projection below. 0 OH I FM 1 g _ j; :1; (are WW) OH OH 4. (3 pts-.) Write a detailed reaction mechanism for the transformation shown below. Use curved arrows to indicate all electron movements, and indicate all format charges clearly. . H0 OCH?» cat. HCI OH OH “300 OCH3 —’3_,_ )4 we) )4 __ \\r f " Q C 63H W m e H’ O OOH3 Chem 308, Summer 2003 Quiza Sections H2 ' v 1. 2 ts. Draw the structure of the ma'or or anic roduct. _ M ( p ) l 9 p (Q, S (m qr \/fi\ H2NNH2. KOH, 200 °c ? 2. {3 pts.) Show how acetal protection is used to perform the synthetic transformation below. Indicate the reagents needed for each reaction and number the reaction conditions separately, as usual. Give intermediate products for partial credit. 0 0H 0 Ci ©th N) White R‘Bi‘rlcg) NAME ID m l'_\ o o ('3 0 UL o O min/{319$ mwog 3.): /\)< ——-—=2 on —--— \i 3. (2 pts.) Draw the structure of the maior organic product. (“a HO OH 0 C) O CH30H, cat. HCl H ’\ O (“3 ? OH OH [ ms J - 0131 03A 4. (3 pts.) Write a detailed reaction mechanism for the transformation shown below. Use curved arrows to indicate all electron movements. and indicate all formal charges clearly. Ho OCHa 0 cat. HCI, H20 tag) it P 9.3 {/43} .. H \ 0 Hgng "V: )‘x s cm ...
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This note was uploaded on 06/25/2009 for the course CHEM 01:160:308 taught by Professor Bokiess during the Spring '09 term at Rutgers.

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Quiz_III_Key - NAME ID K V Chem308,$urnmer2008 Quiz 3...

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