Practice_Quiz_6

Practice_Quiz_6 - Practice Quiz 6(1 Complete the chemical...

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Practice Quiz 6 (1) Complete the chemical reactions below by providing the missing organic product or products within each box. You do not need to show the byproducts of the reactions, or any mechanisms. Be careful to show stereochemical details in the products wherever they are important. Identify products produced as a racemic form. (A) CH 3 H C CH (i) NaNH 2 / liq. NH 3 , -33 o C (ii) CH 3 I C 11 H 18 (B) C C 6 H 5 CH 2 CH 3 H Br + CH 3 S - Na + acetonitrile (100% ee) (100% ee) C 10 H 14 S CH 3 C 6 H 12 O two separable products, each 100% ee CH 3 H Br H H 2 O acetone (C) (100% ee) + CH 3 H C CCH 3 CH 3 C C 6 H 5 CH 2 CH 3 H SCH 3 CH 3 H OH H CH 3 H H OH produced as single enantiomers
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NH 3 , NH 2 - CH 3 CO 2 - , HO - (A) In each pair below, circle the more reactive nucleophile. R OH R OH 2 + R O _ alcohol alkyl oxonium ion alkoxide ion I II III (B) In nucleophilic substitution reactions, the order of reactivity of the leaving groups below will be CH 3 CH 2 CH(CH 3 )CH 2 Br CH 3 CH 2 CH 2 CH 2 CH 2 Br (CH 3 ) 3 CCH 2 Br I II III (C) The reactivity of the alkyl bromides below in an S
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This note was uploaded on 07/22/2009 for the course CHEM 322AL taught by Professor Jung during the Summer '07 term at USC.

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Practice_Quiz_6 - Practice Quiz 6(1 Complete the chemical...

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