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Unformatted text preview: CH 2 =CHCH 3 + H Br CH 3 CHCH 3 Br propene 2-bromopropane CH 3 CH 2 CH 2 Br 1-bromopropane very little formed C=CH 2 CH 3 CH 3 2-methylpropene + H Br CH 3 CCH 3 CH 3 Br 2-bromo-2-methylpropane CH 3 CHCH 2 Br CH 3 1-bromo-2-methyl-propane very little formed Markovnikov's Rule Vladimir Markovnikov (University of Kazan) in 1869: "The hydrogen of the acid attaches to the carbon that already holds the greater number of hydrogens." This prediction is called "Markovnikov's Rule." CH 2 =CH-CH 3 H Br CH 2-CH-CH 3 H Br Markovnikov addition product Addition reactions that follow this rule are called Markovnikov Additions ....
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