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Practice_Quiz_10_blank - Chemistry 322aL Practice Quiz 10...

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Chemistry 322aL Practice Quiz 10 CH 3 CH 2 CHCH 3 CH 3 h ν Cl 2 / Provide all the monochlorination products (1) Provide all the different monochlorination products (treat enantiomers as a single product) of 2-methylbutane and provide their IUPAC names immediately below the structures. Identify any chiral centers in the products with an asterisk and indicate if the product is chiral or achiral.
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If the intrinsic relative reactivities of the H in this reaction are: primary C-H 1.0 secondary C-H 3.0 tertiary C-H 5.0 Estimate the relative amounts of the monochlorination products. CH 3 CH 2 CHCH 3 CH 3 3 H x 1.0 = 3.0 CH 3 CH 2 CHCH 3 CH 3 2 H x 3.0 = 6.0 CH 3 CH 2 CHCH 3 CH 3 1 H x 5.0 = 5.0 CH 3 CH 2 CHCH 3 CH 3 6 H x 1.0 = 6.0
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(2) Photobromination of an alkane is a highly selective reaction in comparison with photochlorination. What is the expected product from the reaction below? CH 3 CH 2 CHCH 3 CH 3 h ν Br 2 / heat A single major product is formed. Explain the greater site selectivity of the bromination reaction by completing the free energy
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This note was uploaded on 07/22/2009 for the course CHEM 322AL taught by Professor Jung during the Summer '07 term at USC.

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Practice_Quiz_10_blank - Chemistry 322aL Practice Quiz 10...

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