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Practice_Quiz_10

Practice_Quiz_10 - Chemistry 322aL Practice Quiz 10(1...

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Chemistry 322aL Practice Quiz 10 CH 3 CH 2 CHCH 3 CH 3 h ! Cl 2 / Provide all the monochlorination products (1) Provide all the different monochlorination products (treat enantiomers as a single product) of 2-methylbutane and provide their IUPAC names immediately below the structures. Identify any chiral centers in the products with an asterisk and indicate if the product is chiral or achiral. ClCH 2 CH 2 CHCH 3 CH 3 + CH 3 CHClCHCH 3 CH 3 + CH 3 CH 2 CCH 3 Cl CH 3 + CH 3 CH 2 CHCH 2 Cl CH 3 * * 1-chloro-3-methyl- butane 2-chloro-3-methyl- butane 2-chloro-2-methyl- butane 1-chloro-2-methyl- butane achiral chiral achiral chiral
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If the intrinsic relative reactivities of the H in this reaction are: primary C-H 1.0 secondary C-H 3.0 tertiary C-H 5.0 Estimate the relative amounts of the monochlorination products. The relative amounts of the products depend on the numbers of chemically equivalent H and their reactivities, which provide a " weighting factor " for the product mixture.
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