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chm2211ps15 - CHM 2211 Problem Set 15 Acids and Acid...

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CHM 2211 Problem Set 15 Acids and Acid Derivatives Complete the reactions by showing major product(s). Write N.R. if no reaction occurs. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. C O OH + NaOH C CH 3 OH O + NH 3 C CH 2 CH 3 OH O + NaH C CH 2 CH 3 OH O SOCl 2 reflux Product from rxn 4 NH 3 Product from rxn 4 CH 3 NH 2 Product from rxn 4 CH 3 CH 2 COONa Product from rxn 4 H 2 O Product from rxn 4 CH 3 CH CH 3 OH Product from rxn 4 NH 2 Product from rxn 4 NH CH 3 CH 3
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12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. CH 3 CH CH CH 3 a. KMnO 4 /OH - /H 2 O/reflux b. HCl CH 2 CH 2 CH 3 OH NaCr 2 O 7 /H + /H 2 O CH O CrO 3 /H + /H 2 O or Ag(NH 3 ) + CH 3 H 3 C a. KMnO 4 /OH - /H 2 O/reflux b. HCl C N H + /H 2 O reflux Br Mg EtOEt CO 2 HCl C CH 3 OH O CH 3 CH CH 3 OH + H 2 SO 4 reflux C CH 3 O O C CH 3 O H 2 O C CH 3 O O C CH 3 O CH 3 OH C CH 3 O O C CH 3 O CH 3 NH 2 C CH 3 O O C CH
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