chm2211ps10sol - CHM 2211 Problem Set 10 Solutions Ketones...

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CH CH 2 CH 2 CH 2 CH 2 CH 3 O CrO 3 , H 3 O+ Acetone, 0°C C O H Ag 2 O, ethanol NH 4 OH, H 2 O CH 3 C CH 3 O H 2 O CHO HCN 1. LiAlH 4 , THF 2. H 3 O+ CHO HCN H 3 O+, heat CH 3 CH 2 C CH 2 CH 3 O CH 3 NH 2 NH CH 3 CH 3 NO 2 NO 2 HN NH 2 + C CH 3 O O H 2 N OH C CH 2 CH 2 CH 2 CH 2 CH 3 OH O COOH + Ag° C H 3 CC H 3 OH OH CH C OH N CH C OH N CH H 2 CN H 2 OH CH COOH OH CH 3 CH 2 C CH 2 CH 3 N CH 3 CH 3 CH C CH 2 CH 3 N CH 3 H 3 C NO 2 NO 2 NH N C CH 3 NO H CHM 2211 Problem Set 10 Solutions Ketones and Aldehydes – Reactions 1 I. Complete the reactions. If no reaction occurs write N.R. 1. 2. 3. 4. 5. 6. 7. 8.
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C O H H 2 N-NH 2 KOH O CH 3 OH excess H 3 O+ CH 3 CH 2 C CH 2 CH 3 O (Ph) 3 P-CHCH 3 THF CHO Cannizzaro Rxn OH CH 3 C
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chm2211ps10sol - CHM 2211 Problem Set 10 Solutions Ketones...

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