{[ promptMessage ]}

Bookmark it

{[ promptMessage ]}

118 C Sample 1 - Chem 118 C SSI 2006 Sample Test-1 Nambiar...

Info iconThis preview shows pages 1–3. Sign up to view the full content.

View Full Document Right Arrow Icon
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full Document Right Arrow Icon
Background image of page 2
Background image of page 3
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: Chem 118 C / SSI / 2006 / Sample Test-1 / Nambiar I. . . Draw the structure of the expected organic omduetCs) fat-med in the following reactions. Unless qtenttoned otherwise. you can assume that all reagents are present in excess. If no teacuon occurs. write “No Reaction“. \ 1) coon H+ C, ~ ——-* ' H ‘ I. CHsMgBr ' 2) R-COOR' _____fi 2 H+ / H20 1. R—Li . "3) CH3COOH _ 4 2. H+IHzo CrOs/HUHO 4) R-CHzOH 2 . l. KCN 5) R—CHzBr I ~ 2.LiA1H4 6) H20 I 0°C RCONHR' .P/ Br: 7) R—CHzCOOH I 8) logo R-OH/Pyridine Go’- 1. [(CH3)2CH-CH2]2A1 H‘ 2. H“ / H20 9) R-COOR' [L Show detailed reaction mechanism for the following reactions. 0 l. N O H O A - ¢ a HI 2 / (621011 § 2. H+IHzo 0 . 2. ' , H“ I H20 I A R-CN _, R-COOH III. Show how on Would carry out the followin unnsf mud h ' magents you would use 1);: each stop and the structure of thgc mmfimoggzuflfgé 1. RCHzBr newcomers; 2. CHéCOOCH3 CH3C0CH3 W. Provide a systematic name or draw the strucmrc as appropriate for the following compounds. 1. .(CH3)2CHCH2COOH 2. N02 —@—COOCH3 3. CH3-CH2-CH(Br)-CONHz 4,. Ethyl 3-aminopmpanoatc . 5. Ethanoic mothanoic anhydridc V. . . Com and A (CsHyozBr) up on heating with neon: sodium hydrondc' followed by acicEgcation with HCl (2M) gave oompound 13071-302319. Compound B up on reacting first with P313 and than dicthyl amine gave compound C (CHI-11401436 wlaoEcpi-oton NMRspocu-um is givcn below. Doduoe the stmcuuu ot'oompoundsA. B In . . ...
View Full Document

{[ snackBarMessage ]}