2009 6 Enol aldol - Chem 2204/2206/2208 Wednesday Jan. 21...

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Chem 2204/2206/2208 Wednesday Jan. 21 Complete Lecture 3 Acetals , Do Lecture 4 on Reversible Carbonyl Additions using Nitrogen and CN. . Friday Jan. 23 Lecture 5 on Irreversible Carbonyl Additions ; Test topics ednesday, Jan28 ecture 6 on ldol eview TODAY! 1 Wednesday, Jan28 Lecture 6 on Aldol; Review Friday Jan 30 Test 1 on Lectures 1- 6, 11:35 – 12.55 Test will be held in Theatre B. Sample test 1 and Answers posted on http://http-server.carleton.ca/~pbuist/
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Carbonyls and Enol (Enolate) Reactions . euterium xchange 2 9. Deuterium exchange 10. α - Halogen ation 11. α -alkylation 12. Ald ol formation Lecture 6 2009
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Assignment 2 (McMurry 6e) Topic Chapter Section Problems Enol formation 22.1 22.1 a,d,f, 22.2, 22.3 Alpha Bromination and Deuterium Exchange 22.2, 22.3 22.4, 22.5, 22.31 Enolate formation 22.5, Table 22.1 22.7 a,b,c, 22.8, 22.32 3 Iodoform formation 22.6, 22.7 22.9, 22.10, 22.30 Aldols 23.1, 23.2 23.1, 23.2, 23.27 Enones from Aldols 23.4 23.3, 23.4 Conjugate Addition 19.14 19.19, 19.20 Aldols in synthesis 23.5, 23.6, 23.7 23.5, 23.27, 23.29, 23.35
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Assignment 2 (McMurry 7e) Topic Chapter Section Problems Enol formation 22.1 22.1 a,d,f, 22.2, 22.3 Alpha Bromination and Deuterium Exchange 22.2, 22.3 22.4, 22.5, 22.29 Enolate formation 22.5, Table 22.1 22.7 a,b,c, 22.8, 22.30 4 Iodoform formation 22.6, 22.7 22.9, 22.10, 22.28 Aldols 23.1, 23.2 23.1, 23.2, 23.27 Enones from Aldols 23.3 23.3, 23.4 Conjugate Addition 19.13 19.21, 19.22 Aldols in synthesis 23.4, 23.5, 23.6 23.5, 23.6, 23.8, 23.27, 23.29, 23.35
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and Ketones 1. 1,1- halo hydrin formation 2. a) Hydration b) Acetal formation 3. a) Imine formation 8. a) O xidation with Jones Reagent (Aldehydes) b) Bayer-Villiger o xidation (Ketones) 5 b) En amine formation 4. Cya n ohydrin formation
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This note was uploaded on 07/28/2009 for the course ORGANIC CH CHEM 2204 taught by Professor Dr.levin during the Winter '08 term at Indian Institute of Technology, Chennai.

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2009 6 Enol aldol - Chem 2204/2206/2208 Wednesday Jan. 21...

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