2009 9 Carboxylic Acid _Family III - Carboxylic Acid Family...

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Carboxylic Acid Family 1 Reactions Part 3-Chapters 21-23 Test 1 Answers now posted on website! http://http-server.carleton.ca/~pbuist/
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Chem 2204/2206/2208 Feb 11 Lecture 9 Carboxylic acids III TODAY! Feb 13 Lecture 10 Carboxylic acids IV Feb 16 – 20, Study Break 2 Wednesday, Feb 25 Review lecture – go over sample test Friday Feb 27 Test 2 on Carboxylic Acids (Lectures 7-10), 11:30 – 1.00 Test 2 covers only Carboxylic Acids . Sample test is posted on http://http-server.carleton.ca/~pbuist/
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Assignment (McMurry 6( 7 ) th Edition) Topic Chapter Section Problems Top Ten except for Claisen 21.3-21.7 21.3, 21.( 5 )6, 21.8( 7 )- 21.10( 9 ), 21.13( 12 ), 21.17( 16 ), 21.19 ( 18 ), 21.36 a-e,g,h laisen 3.8 ( 3.10( 3.11 a, 23,12, 23.14, 3 Claisen 23.8 ( 7 ) -23.10( 9 ), 23.14( 13 ) 23.11 a, 23,12, 23.14, 23.40 Acetoacetate and Malonic Esters in Synthesis and Biosynthesis 22.( 7 ), 29.7 22.11a( 10a ), 22.14( 13 ), 29.14( 5 )
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Top 10 reactions of Carboxylic Acid and Derivatives 1. Hydro lysis (a-e) 2. Synthesis of acid chlorides 3. Synthesis of acid anhydrides 6. Grignard Reaction 7. Reduction 8. Alkylation of β -keto esters or diesters . Claisen Reaction 4 4. Synthesis of esters (a-c) 5. Synthesis of Amides (a,b). 9. (like Aldol) 10. Decarboxylation of β -keto acids
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Recall Fatty Acid Derivative hydrolysis R Cl O R O R O O O O H 2 O H 2 O H 2 + + + Rxn # 1a-d 5 R O R N O R' R OH O O H 2 + R H
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“Simplified” view of hydrolysis vrs synthesis R Cl O R O R O O O O H 2 O H 2 O H 2 + + + Rxn # 1a-d Rxns 6 R O R N O R' R OH O O H 2 O H 2 O H 2 O H 2 O H 2 R O O + - - - - Cl R H H H O H R N H 2 R' # 2-5
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This note was uploaded on 07/28/2009 for the course ORGANIC CH CHEM 2204 taught by Professor Dr.levin during the Winter '08 term at Indian Institute of Technology, Chennai.

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2009 9 Carboxylic Acid _Family III - Carboxylic Acid Family...

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