2009_17_Stereochemistry_2204 - Chem 2204/2206/2208...

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Chem 2204/2206/2208 Wednesday Mar 25 Lecture 17 on Stereochemistry (I) TODAY! Friday Mar 27 Lecture 18 on Stereochemistry (II). Wednesday, April 1 Optional review lecture – go over sample Exam and problems; Exam topics etc. Friday April 3 Lab Exam Theatre B 11:30 – 12.30
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Stereochemistry McMurry 6e, (7e) Topic Chapter Section Problems Isomers (Overview) 9.11 (9.9) Enantiomers (Chirality) 9.1-9.2 9.2, 9.3, Optical Activity 9.3, 9.4 Absolute ( R , S ) vrs Relative Configuration( D , L ) 9.5, 25.2-25.3, 26. 1 9.8( 9 ) Diastereomers 9.6-9.9 ; (9.6, 9.7) 9.12( 13 ), 9.14 ( 15 ) Resolution of Enantiomers 9.4, 9.10 (9.8) 9.18 ( 9.18, 9.19 ) Distinguishing between “identical” groups or faces 13. 8
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Recall: There are two parts to Organic chemistry: Structure and Reactivity ; Stereochemistry is an important component of Structure (A) Structure: 1. Functional groups . tereochemistry 2. Stereochemistry 3. Electronic factors affecting reactivity and physical properties (B) Reactivity: 1. ABENOR 2. Mechanism 3. Synthesis
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Isomer Classification ( McMurry 9.9 ) Constitutional or Structural isomers (different bond connectivity) Stereoisomers (different spatial arrangement) Isomers (same Mol Formula, different structure) Conformational Configurational Isomers (interconvert by bond rotation) Isomers (interconvert
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2009_17_Stereochemistry_2204 - Chem 2204/2206/2208...

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