Outline_6_chpts_11_12

Outline_6_chpts_11_12 - CHEM 2250 Outline #5 Chapters 11...

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CHEM 2250 Outline #5 Chapters 11 and 12 CHAPTER 11 I. Alcohols Classification sec. 11.1 II. Reduction and Oxidation of Alcohols a. Hydrogenation of aldehydes and ketones sec. 11.10 b. Metal hydrides reduction sec. 11.10 c. Oxidation of alcohols with Cr(VI) reagents sec. 11.18 III. Formation of Alcohols by Reductive Alklyation of Aldehydes and Ketones sec. 11.7 and 11.8 a. Formation of organolithium and organomagnesium (Grignard) reagents b. Addition of organometallics to aldehydes and ketones to form alcohols IV. Substitution reaction of Alcohols to make Halides sec. 11.17 V. The Grignard Reaction Revisited; Making Bigger Alcohols from Smaller Alcohols Problems: 1-5, 7-19, 22, 23(b&c), 24, 26-30, 32, 35, 36, 38-44, 46 CHAPTER 12 I. Introduction to Nucleophilic Substitution sec. 12.1 II. The S N 2 Reaction a. Mechanism: rate law, stereochemistry and transition state sec. 12. 2 b. Nature of the substrate sec. 12.4 c. Nucleophilicity sec. 12.4 d. Leaving groups sec. 12.4 i. S N 2cA, reaction of alcohols with hydrogen halides
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Outline_6_chpts_11_12 - CHEM 2250 Outline #5 Chapters 11...

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