104A Sp09 lecture 14

104A Sp09 lecture 14 - ABABAB Stacking of Graphite"staging...

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ABABAB Stacking of Graphite
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graphite + potassium “staging” insulator copper- colored blue high electrical conductivities
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Redox Intercalation Co Fe 2+
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Li X (X = Cl, Br, NO 3 ) Intercalation of Lithium Salts in Gibbsite γ -Al(OH) 3 [LiAl 2 (OH) 6 ]Cl . H 2 O 11.6 Å 6.7 Å Unique example of intercalation of both anions and cations into a layered host The product is a very rare example of an ordered layered double hydroxide Chem Mater. , (1997), 9 , 241 H 2 O, RT
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Structure of Gibbsite: γ -Al(OH) 3
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Structure of Gibbsite LiCl Intercalate
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Intercalation of Pharmaceuticals in [LiAl 2 (OH) 6 ]Cl . H 2 O [LiAl 2 (OH) 6 ]Cl . 2H 2 O 22.3 Å 23.2 Å Naproxen Diclofenac GemFbrozil -Cl , H 2 O/ 80 °C -Cl , H 2 O/ 80 °C -Cl , H 2 O/ 80 °C Chemical Communications , (2001), 2342 21.5 Å OH O O O O O NH O Na + O HN O O O OH O O O O
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Edge Dislocation B. A. Vacancy Dislocation Substitutional Interstitial Crystalline Defects A screw dislocation
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104A Sp09 lecture 14 - ABABAB Stacking of Graphite"staging...

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