Friday_Session_1

Friday_Session_1 - electrons in each step 1 AlCl 3 2 H 3 O...

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Chem 3580 Spring 2009 Friday Session - Week #1 For some of the questions you may have to go back and review Chem 357 materials. 1. Suggest a suitable synthesis for each of the following compounds beginning with benzene and suitable organic (containing no more than 4 carbon atoms) and inorganic reagents. O COOH NH 2 (E) (A) (B) (C) (D) (F) 2. Suggest a mechanism for the reaction shown below that accounts for the indicated stereochemical result. H HO CH 3 O H CH 3 1. AlCl 3 2. H 3 O + + 3. Write a stepwise mechanism for each of the following reactions. Use curve arrows to show the flow of
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Unformatted text preview: electrons in each step. + 1. AlCl 3 2. H 3 O + CH 2 Cl 2 4. The insecticide dichlorodiphenyltrichloroethane (DDT) has been made in ton quantities by the reaction shown below. Formulate a detailed stepwise mechanism for the reaction. Use curved arrow formalism to show electron flow. CCl 3 Cl Cl Cl 3 C H O 99% H 2 SO 4 , 15°C, 5 hr Cl DDT 98% + H 2 O...
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