Practice Midterm 1

Practice Midterm 1 - Name TU ID Organic Chemistry 2201 MWF...

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Name_________________________________  TU ID#______________________________ Organic Chemistry 2201.  MWF: Midterm 1 Practice.  Chapters 1-5 1.  Assign R or S configuration to the following molecules.   NH 2 O H O         CH 3 OH H C H 3 NH 2 O C H 3 2.  Label whether the following alkenes are E or Z isomers.  Cl Br I 3.  Draw the curly arrows to show the flow of electrons that convert the reactants to the products.  a.   H Cl + Cl - Cl b.  Cl + I - I Cl - + c.   Cl Cl Cl H -OH + Cl Cl : + O H 2 + Cl - 1
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4.  What products would the following reactions form?  Include any stereochemistry in your  answer.  2 . N a B H 4 1 .   B H 3 ,   T H F 2 .   H 2 O 2 ,   - O H ,   H 2 O H 2 ,   P d / C 1 .   H g ( O 2 C C F 3 ) ,   C H 3 O H C l 2 C H 2 C l 2 5.  Propose a suitable curly arrow mechanism for the hydration of an alkene through  oxymercuration.   1 .   H g ( O A c ) 2 ,   H 2 O 2 .   H 2 O 2 ,   - O H ,   H 2 O 2
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6.  In terms of stability, rank the following species from 1 to 4 (1 
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