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Unformatted text preview: 1 CHAPTER 11 Reactions in Aqueous Solutions II: Calculations 2 Chapter Goals Aqueous AcidBase Reactions 1. Calculations Involving Molarity 2. Titrations 3. The Mole Method and Molarity 4. Equivalent Weights and Normality OxidationReduction Reactions OxidationReduction Reactions 1. The HalfReaction Method 2. Adding in H + , OH , or H 2 O to Balance Oxygen or Hydrogen 3. Stoichiometry of Redox Reactions 3 Calculations Involving Molarity Example 111: If 100.0 mL of 1.00 M NaOH and 100.0 mL of 0.500 M H2SO4 solutions are mixed, what will the concentration of the resulting solution be? What is the balanced reaction? It is very important that we always use a balanced chemical reaction when doing stoichiometric calculations. 4 Calculations Involving Molarity Reaction Ratio: 2 mmol 1 mmol 1 mmol 2 mmol Before Reaction: 100 mmol 50 mmol 0 mmol 0 mmol After Reaction: 0 mmol 0 mmol 50 mmol 100 mmol O H 2 SO Na SO H + NaOH 2 2 4 2 4 2 + 5 Calculations Involving Molarity What is the total volume of solution? 100.0 mL + 100.0 mL = 200.0 mL What is the sodium sulfate amount, in mmol? 50.0 mmol What is the molarity of the solution? M = 50 mmol/200 mL = 0.250 M Na 2 SO 4 6 Stoichiometry of AcidBase Reactions 2 NaOH + H 2 SO 4 Na 2 SO 4 + 2 H 2 O (NaOH) + (H 2 SO 4 ) (OH ) + (H+) (Na 2 SO 4 ) + (H 2 O) (H 2 O) Note: Height proportional to moles for equivalent amounts of acid and base Width greater for multiple equivalents of a constituent e. g. H + or OH Formula equation Net ionic equation 7 Calculations Involving Molarity Example 112: If 130.0 mL of 1.00 M KOH and 100.0 mL of 0.500 M H 2 SO 4 solutions are mixed, what will be the concentration of KOH and K 2 SO 4 in the resulting solution? What is the balanced reaction? 8 Calculations Involving Molarity 2 KOH + H SO K SO + 2 H O 2 4 2 4 2 Reaction Ratio: 2 mmol 1 mmol 1 mmol 2 mmol Before Reaction: 130 mmol 50 mmol 0 mmol 0 mmol Consumed 100 mmol 50 mmol After Reaction: 30 mmol 0 mmol 50 mmol 100 mmol 9 Calculations Involving Molarity What is the total volume of solution? 130.0 mL + 100.0 mL = 230.0 mL What are the potassium hydroxide and potassium sulfate amounts? 30.0 mmol & 50.0 mmol What is the molarity of the solution? M = 30.0 mmol/230.0 mL = 0.130 M KOH M = 50.0 mmol/230.0 mL = 0.217 M K 2 SO 4 10 Calculation Steps For Reaction 1. Find the limiting reactant 2. Determine moles of other reactant needed to react with it 3. Subtract number of moles of all reactants consumed 4. Determine moles of each reactant left 5. Determine moles of products 6. Determine final volume 7. Divide moles by volume Molar concentration 11 Calculations Involving Molarity Example 113: What volume of 0.750 M NaOH solution would be required to completely neutralize 100 mL of 0.250 M H 3 PO 4 ?...
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This note was uploaded on 09/20/2009 for the course CHEM 344 taught by Professor Denniston during the Spring '09 term at University of Georgia Athens.
 Spring '09
 Denniston
 Molarity, Mole, AcidBase Reactions

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