Organic%20Chemistry%20I%20%20CHM2210%20Test%203

Organic%20Chemistry%20I%20%20CHM2210%20Test%203 - TEST 3...

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TEST 3 ( Version A) 1. Give the IUPAC names of the following compounds. Use E/Z OR cis/trans designation where appropriate (20 pts). a) Bicyclo[2.2.2]oct-2-ene b) ( E )-3-methyl-1,3-pentadiene c) 2-Ethyl-1,3-cyclohexadiene d) H 2 C CHC(CH 3 ) 2 CH C CH 2 CH 2 CH 3 C H H CH 2 CH 3 cis -3,3-Dimethyl-4-propyl-1,5-octadiene e) ( 1-Methylethenyl)cyclopentene or ( 1-Methylvinyl)cyclopentene
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2 2. Draw structures corresponding to the following names (12 pts). a) (3E, 5E)-1,3,5-octatriene b) 2,3-Dimethyl-2-heptene c) trans -2,2,5,5-Tetramethyl-3-hexene CC H C(CH 3 ) 3 H (H 3 C) 3 C 3. Predict the structure of the alkene you would use to prepare each alkyl halide below. ( 6 pts) I. Answer: II. Answer: Br (only product) CH 3 CHCH 2 3 II
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3 4. The structures below show the step-wise bond making and bond breaking in this reaction. (3 pts). Calculate K eq for the reaction. Answer: K eq products reactants == = 76 24 317 . 5. Draw and name the structure of the product when 1,2-dimethylcyclohexene is treated with H 2 and PtO 2 in CH 3 COOH. The stereochemistry of the product must be shown (5 pts).
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This note was uploaded on 09/21/2009 for the course CHM 2210 taught by Professor Staff during the Summer '08 term at University of Central Florida.

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Organic%20Chemistry%20I%20%20CHM2210%20Test%203 - TEST 3...

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