KEYS%20to%20Project%207%20for%20Summer%202009

KEYS%20to%20Project%207%20for%20Summer%202009 - CH.H STRY...

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Unformatted text preview: CH .H STRY 3613 Summer, 2009 Project 7 0w N H3; CHCOO" ol— Coo.“ a. 0 ' on my C;- 9 aftio: y Rfifimfi 3 9 1. Draw Aspartic acid at a pH of M “ii” “491 (1;, a) 3.0 b) 11.0” mm ; RBI-DCiJJCOO" #0” (furoo- 3’4““) CMa (00H CHaCoo ‘ 25: dove... new; eff-53.9 fiflgiu/J ‘5 2. Which is the stronger acid, goicacfior para-hydroxybenzoic acid? Use resonance forms to explain your answer. " 0—0167 wfl'afiuj OG‘O'CP— f " ‘6'?” 85"55‘: L W‘ “an H /C,5- a...) ICE-Wm é) 3 7L Clam Q:0€¢91w14 Wain-Ea C35. ffi‘LQK OYZW 3. How would you prepare 2, 6-dichlorobenzoic acid from benzene? Use a blocker to cut down one“ mixes of Isomers. 5 0‘3 £3465 7—3519 803 H CW“ CH3 U CH3 I CL! C d! [1094 7105, C, Cl HLO’ 14+ .. a 0 0—— . 4—? We a W 503 H” X 2" 2. Use resonance forms to explain why the compound below is less reactive than aniline in a reaction with Br; and FeBrg. NHCOCH3 @{baa Am pm. I Mafid "é f-Infi 699nm l Ely-g“: ca, 2:; N Na“) Com. 03" / ,’_ Q20 So #255 v 4. N:- ccfl . flc ‘ 3 1% h 14:5 a'fi‘e 3. In each pair circle the more acidic member AND explain your choices. 00131. Add gator" . @COO' CH3 Q*MC€&MI(‘203 Call, W5M(zagcé a) p- -methylbenzoic acid or Q-chlorobenzoic a9 W12 59,41.th c E. :3 5W1?" b)_acid or 3- chlorobutanoic acidJ MON- CI [5 Eflmfl closer 11449-441. T “Wu/1% 0.42% )hMOL-i LQ.w}‘HLoé1cI-.oovxj cg We} Inca—1% flea/Q ’I ...
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