exam1summer00 - Page 1 of 4 Chemistry 51 Exam 1 Summer 2000...

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Page 1 of 4 Brooklyn College, CUNY Chemistry 51, Exam 1, Summer 2000 Chemistry 51 Exam 1 Summer 2000 This is a closed book exam. All answers must be put on the answer sheet. Only the answer sheet will be collected. Write your name on the answer sheet now . Give the name of the two following compounds. Include pertinent stereochemical designation for chiral carbons in question 2. 1. CO 2 H HO 2 C 2. CO 2 H CO 2 H CH 3 HO CH 3 HO 3 a) Is the compound in question 2 optically active? b) How many stereoisomers are there, including the structure shown, for the molecule in question 2? 4. Which of the structures A-D represent the same molecule as structure 1 ? Answer by letter. 1 A B C D H H H H H Cl Cl Cl Cl Cl F F F F F Br Br Br Br Br
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Page 2 of 4 Brooklyn College, CUNY Chemistry 51, Exam 1, Summer 2000 5. Which of the following is the strongest acid and which is the weakest acid? Answer by letter. NH 3 OH 2 FH A B C ClH D 6. Consider the free radical monochlorination of CH 3 D, where D is the deuterium
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