I Can Make Alcohols

I Can Make Alcohols - a Br O HO b NaNH 2 O H c Cl Mg O O d...

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I Can Make Alcohols Alkyne Reactions R R R R Br Br 2NH 2 2NH 2 R R Br Br H 2 O/H Hg 2 O Br 2 R Br R Br Br 2 R R Br Br Br Br HBr R Br R H HBr H 2 Lindlar's Pd/CaCO 3 R H H R trans H 2 /Pd R R H H H H Na/NH 3 R H R H trans cis H H O 3 /H 2 O R OH O 2 Alkene Reactions H 2 Br Br Br 2 OH HBr Br(Cl) HBr (HCl) O OH HO OH O H O Cl OH H H H 2 O/H + E1 or E2 KMnO 4 /H + 2 KMnO 4 /OH - E1 or E2 1. O 3 , H 2 O/Zn 2 RCO 3 H Cl 2 /H 2 O or PBr 3 or SOCl 2 Base 1. B 2 H 6 2. H 2 O 2 /OH Br H ANTI- Markovnikov OH H HBr/R 2 O 2 Note: the cis and trans orientation can only be seen in ring structures that prevent free rotation around the C–C single bond.
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1. Fill in the missing reagent(s) or product(s) obtained after workup.
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Unformatted text preview: a. Br O HO b. NaNH 2 O H c. Cl Mg O O d. KMnO 4 /OH e. KMnO 4 /H Li excess f. 1. O 3 Li 2. Zn/H 2 O g. NaNH 2 Br H 2 O/H h. Show the mechanism of the reactions in 1.g. 2. Show how you would synthesize the following compounds. No restrictions are imposed unless otherwise stated. a. Br + Br OH OH b. CH 3-I CH 3-OH c. Br OH OH HO d. CH 3-I OH e. OH f....
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I Can Make Alcohols - a Br O HO b NaNH 2 O H c Cl Mg O O d...

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