Untamed Organic Mix II Test 3

Untamed Organic Mix II Test 3 - detailed mechanism for this...

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Untamed Organic Mix II Test 3 1. Fill in the blanks for the following reactions. If you believe, without doubt, that no reaction will occur, please say so. a. Cl KCN, H H 2 O/H b. O NH 2 LAH c. O O O NH 2 H d. Cl O 1 MgCl NH 2 -78°C NaBH 3 CN e. O H HO OH H Cl Mg O HCl H 2 O/H 1. PPh 3 2. BuLi
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f. Show the sequence of steps that leads to your product. g. O NH 2 H 2 O/H SOCl 2 H N h. O MCPBA MCPBA = Cl O O OH 2. A variation of the Strecker amino acid synthesis reaction is shown below. Dating back to 1850, it is one of the oldest synthetic methods in organic chemistry. Please show a
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Unformatted text preview: detailed mechanism for this reaction. R H O 1. NH 3 , HCN 2. H 2 O/H R H 2 N H O OH 3. Show how you would do the following transformations. All additional reagents are available unless otherwise restricted. a. H O + NH 3 + HCN NH 2 NH 2 b. O OH NH 2 c. S S N H N + Br Br + d. Br OH OH e. + 4. Just do them, and do them fast. O H NH 2 H Ag /NH 3 KCN/H LAH H N H HO OH H...
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This note was uploaded on 09/25/2009 for the course CH 223 taught by Professor Brown during the Spring '08 term at N.C. State.

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Untamed Organic Mix II Test 3 - detailed mechanism for this...

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