CHEM 212 Lecture 8

CHEM 212 Lecture 8 - 9/24/2009 ORGANIC CHEMISTRY 212...

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9/24/2009 1 ORGANIC CHEMISTRY 212 Youla S. TSANTRIZOS Office: Chemistry Department Email: youla.tsantrizos@mcgill.ca Lecture 8 : September 24 th , 2009 ORGANIC CHEMISTRY 212 Chapter 6: Substitution / Elimination reactions - alkyl halides - alcohols
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9/24/2009 2 Dipoles δ δ δ - δ + δ + Electrostatic Potential Map Bleu is electropositive Red is electronegative White is neutral Electrostatic Potential Maps & Dipoles .
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9/24/2009 3 . Electrostatic Potential Maps & Dipoles Dipoles δ δ δ - δ +
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9/24/2009 4 Separation of Enantiomers - Resolution δ δ δ - δ + Separation of Enantiomers - Resolution H + - Diastereomeric Salts
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9/24/2009 5 Bond Length and Bond Strength F 2 Cl 2 Br 2 I 2 Atomic Orbitals
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9/24/2009 6 Bond Length and Bond Strength F 2 Cl 2 Br 2 I 2 Bond Length (Å) 1.39 1.78 1.93 2.14 Bond Strength (kJ/mol) 472 350 293 239 Bond Length and Bond Strength Bond Length (Å) 1.39 1.78 1.93 2.14 Bond Strength (kJ/mol) 472 350 293 239 I + - F + - this is not a spontaneous reaction
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This note was uploaded on 10/16/2009 for the course CHEM CHEM212 taught by Professor T during the Fall '09 term at McGill.

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CHEM 212 Lecture 8 - 9/24/2009 ORGANIC CHEMISTRY 212...

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