Practice_Quiz_12

Practice_Quiz_12 - Chapter 12 Practice Quiz with solutions

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Complete the reactions below by providing the missing products inside the boxes. Be careful to give all the important organic products, as requested. It is not necessary to give the byproducts of the reactions. Stereochemical details in the products must be indicated, wherever they are important. "Workup" means treatment with water and bringing the reaction mixture to neutral pH. (1) Chemistry 322aL Practice Quiz 12 (A) HCCH 2 CHCH 2 COCH 3 O = O CH 3 + NaBH 4 H 2 O, CH 3 OH (B) CH 2 OH CH 3 + N . CrO 3 . HCl (PCC) CH 2 Cl 2 C 8 H 8 O HOCH 2 CH 2 CHCH 2 COCH 3 CH 3 O CHO CH 3
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(C) CH 3 CH 2 CH 2 CH 2 Br (i) Mg/dry ether (ii) CH 3 CCH 3 O = (iii) workup C 7 H 16 O (D) CH 3 CHCH 2 CH 2 Br CH 3 (i) Mg/dry ether (ii) CH 2 CH 2 O (iii) workup (E) CH 3 CH 2 COCH 2 CH 3 O (i) excess CH 3 CH 2 MgBr/dry ether (ii) workup C 7 H 16 O CH 3 CH 2 CH 2 CH 2 CCH 3 CH 3 OH CH 3 CHCH 2 CH 2 CH 2 CH 2 OH CH 3 CH 3 CH 2 CCH 2 CH 3 CH 2 CH 3 OH
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CH 3 CH 2 COCH 3 O = CH 3 CH 2 COH CH 3 CH 3 (2) Answer the questions below. (A) What are the formal oxidation states of each carbon atom
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Practice_Quiz_12 - Chapter 12 Practice Quiz with solutions

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