Practice_Quiz_15_blank

Practice_Quiz_15_blank - benzene and 1-butanol. + CH 3 CH 2...

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(A) CH 3 (i) HNO 3 , H 2 SO 4 , heat (ii) workup + (B) COOH (i) Br 2 , Fe (ii) workup two major products C 7 H 5 O 2 Br Practice Quiz 15 (1) Provide the organic products of the following reactions, as requested. (C) CH 3 (i) hot aqueous KMnO 4 , KOH (ii) workup
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p-nitrophenol 3-chloro-4-methylaniline (2) Provide structures inside the boxes for the two aromatic compounds indicated below. (3) Draw the resonance structures that contribute to the hybrid of the intermediate arenium ion in the ortho-chlorination of phenol. OH arenium ion Cl 2 Fe OH Cl
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(4) Show the formation of the "effective electrophile" in the following cases: bromination Br 2 Fe nitration HNO 3 /H 2 SO 4 Friedel-Crafts Acylation RCOCl/AlCl 3
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(5) Design a practical synthesis of butylbenzene from
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Unformatted text preview: benzene and 1-butanol. + CH 3 CH 2 CH 2 CH 2 OH (6) In each pair of structures below, select the more stable chemical species. + + CH 2 CH 2 CHCH 3 + + . . (7) Provide the major organic product of the reactions below. (A) CH 2 CH 2 CH 2 CH 3 NBS CCl 4 h + C 10 H 13 Br (B) + HBr no peroxides ionic addition (C) OH H + heat C 9 H 10 (D) CH 3 Na liq NH 3 , EtOH C 7 H 10 (8) Indicate the site or sites of nitration in the following disubstituted benzenes. CH 3 CH 3 Br Cl CCH 3 NO 2 O = OCH 3 NO 2 O NHCCH 3 SO 3 H (9) Design syntheses of p-chloronitrobenzene and m-chloronitrobenzene from benzene and any other needed reagents....
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Practice_Quiz_15_blank - benzene and 1-butanol. + CH 3 CH 2...

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