Practice_Quiz_18_blank

Practice_Quiz_18_blank - Chapter 18 practice quiz (blank)

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Practice Quiz 18 (1) Provide the products of the following reactions. (A) CH 3 CH 2 CH 2 CH 2 Br (i) Mg/ether (ii) CO 2 (iii) H 3 O + (B) C 6 H 5 CHCH 3 OH (i) Cl 2 ,NaOH, H 2 O (ii) H 3 O + (C) C 6 H 5 CH 2 Br (i) NaCN (ii) H 3 O + , H 2 O, heat O O O + CH 3 CH 2 CH 2 CH 2 OH (excess) heat (D) (E) CH 3 CH 2 CH 2 COOH (i) SOCl 2 (ii) 2 eq (CH 3 ) 2 CHCH 2 NH 2
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(2) Provide IUPAC names for the following compounds. C 6 H 5 CHCH 2 CH 2 COOH CH 3 COOH CH 3 CH 2 CO 2 C 6 H 5 CO 2 CH 3 Cl CH 3 CH 2 CH 2 CCl O = CH 3 CH 2 CNHCH 3 O CH 3 CH 2 CH 2 CH 2 CN
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RCO 2 H + CH 3 CH 2 OH cat H + RCO 2 CH 2 CH 3 + H 2 O CH 3 CH 2 CH 2 CH 2 COOH CH 3 CH 2 CHCOOH CH 3 CCOOH CH 3 CH 3 CH 3 I II III I>II>III III>II>I III>I>II they all proceed at the same rate CH 3 CH 2 CHCOOH C 6 H 5 (S) (100% ee) + CH 3 CH 2 CHNH 2 CH 3 (S) (100% ee) + C 6 H 11 N=C=NC 6 H 11 ether solvent a single diastereomer (S)(S) a single diastereomer (R)(R) a single diastereomer (S)(R) a single diastereomer as a racemic form (S)(S) and (R)(R)
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This note was uploaded on 10/20/2009 for the course CHEM 322BL at USC.

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Practice_Quiz_18_blank - Chapter 18 practice quiz (blank)

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