{[ promptMessage ]}

Bookmark it

{[ promptMessage ]}

Chapter24-Isomrs

Chapter24-Isomrs - Coordination Sphere[Co(NH3)6 3[Ni(CN)4]2...

Info icon This preview shows pages 1–8. Sign up to view the full content.

View Full Document Right Arrow Icon
Coordination Sphere [Co(NH 3 ) 6 ] 3+ [Ni(CN) 4 ] 2-
Image of page 1

Info icon This preview has intentionally blurred sections. Sign up to view the full version.

View Full Document Right Arrow Icon
Isomers Pt(NH 3 ) 2 Cl 2 cis - PtCl 2 (NH3) 2 trans -Pt Cl 2 (NH 3 ) 2 Geometric Isomers same formula different properties
Image of page 2
Biological Importance of Being cis cis -PtCl 2 (NH 3 ) 2 antitumor agents trans -PtCl 2 (NH 3 ) no effect on tumors. synthesis of drugs -obtain correct isomer Why cis? Geometric significant (easier to coordinate to adjacent bases on DNA once cis ligands are lost.)
Image of page 3

Info icon This preview has intentionally blurred sections. Sign up to view the full version.

View Full Document Right Arrow Icon
Isomers ( same formula but different properties ) Structural Isomers ( different bonds ) Stereoisomers ( same bonds, different spatial arrangements ) Ionization Coordination Linkage Geometric ( cis, trans ) Optical
Image of page 4
Structural Isomers ( different bonds ) Ionization Isomers   - differ by the exchange of a ligand with   an anion or neutral molecule outside the coordination sphere. [Co Br (NH 3 ) 5 ] SO 4 [Co SO 4 (NH 3 ) 5 ] Br Co 3+ NH 3 NH 3 NH 3 NH 3 NH 3 Br SO 4 Co 3+ NH 3 NH 3 NH 3 NH 3 NH 3 Br SO 4
Image of page 5

Info icon This preview has intentionally blurred sections. Sign up to view the full version.

View Full Document Right Arrow Icon
Structural Isomers ( different bonds ) Ionization Isomers   - differ by the exchange of a ligand with   an anion or neutral molecule outside the coordination sphere.
Image of page 6
Add Ba 2+ ?? White ppt Structural Isomers ( different bonds ) Ionization Isomers   - differ by the exchange of a ligand with   an anion or neutral molecule outside the coordination sphere.
Image of page 7

Info icon This preview has intentionally blurred sections. Sign up to view the full version.

View Full Document Right Arrow Icon
Image of page 8
This is the end of the preview. Sign up to access the rest of the document.

{[ snackBarMessage ]}

What students are saying

  • Left Quote Icon

    As a current student on this bumpy collegiate pathway, I stumbled upon Course Hero, where I can find study resources for nearly all my courses, get online help from tutors 24/7, and even share my old projects, papers, and lecture notes with other students.

    Student Picture

    Kiran Temple University Fox School of Business ‘17, Course Hero Intern

  • Left Quote Icon

    I cannot even describe how much Course Hero helped me this summer. It’s truly become something I can always rely on and help me. In the end, I was not only able to survive summer classes, but I was able to thrive thanks to Course Hero.

    Student Picture

    Dana University of Pennsylvania ‘17, Course Hero Intern

  • Left Quote Icon

    The ability to access any university’s resources through Course Hero proved invaluable in my case. I was behind on Tulane coursework and actually used UCLA’s materials to help me move forward and get everything together on time.

    Student Picture

    Jill Tulane University ‘16, Course Hero Intern