ANSWS_KEY_PROB_SET_2

ANSWS_KEY_PROB_SET_2 - CEM 351 Fall 2008 - Prof. Rathke--...

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CEM 351 Fall 2008 - Prof. Rathke -- Answers -- 2nd Sample Problem Set (Chapters 6, 7, 8, 9) NOTE: #16 & 18 are derived from Chapt. 10 & won’t be covered on the Exam. 1. a) b) c) d) e) Cl C CHCH 2 CH 3 CH 3 CH 2 Cl C CH 2 CH 2 CH 3 CH 3 CH 2 C CCH 2 CH 3 CH 3 CH 2 Cl Br C CCH 2 CH 3 CH 3 CH 2 Br Br Br Br (1 mol) (2 mol) (1 mol) (2 mol) Br 2 Br 2 3-hexyne Br excess H 2 ,Pd hexane HCl HCl f) g) h) i) j) O C CH 2 CH 2 CH 3 CH 3 CH 2 H 2 ,Pd BaSO 4 , Quinoline C H H CH 2 CH 3 CH 3 CH C CH 2 CH 3 H CH 3 CH Li/NH 3 H 2 O 1) 2) BH 3 NaOH, H 2 O 2 1) 2) O C CH 2 CH 2 CH 3 CH 3 CH 2 No reaction H 2 O, H 2 SO 4 HgSO 4 , NaNH 2
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CEM 351 - Dr. Rathke, Fall 2008 – Answers - 2nd Sample Problem Set. ... page 10 19. CH 3 CH CHCH 2 NH 2 CH 3 CH CHCH 2 N CH 3 CH 2 CH 3 CH 3 CH CHCH 2 CH 3 CH 3 CH CHCH 2 S Ø CH 3 CH CHCH 2 CH 3 CH CHCH 2 O C CH 3 CH 3 CH CHCH 2 C C Ø CH 3 CH CHCH 2 OCH 3 CH 3 CH CHCH 2 OH CH 3 CH CHCH 2 C N CH 3 CH CHCH 2 O C H O O N , , , , , , , C N , O C H O N OH and OCH 3 , O CCH 3 , CH 3 , O C C Ø , H Z where Z is NH 2 , SØ , N CH 3 CH 2 CH 3 , 20.
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CEM 351 - Dr. Rathke, Fall 2008 – Answers - 2nd Sample Problem Set.
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This note was uploaded on 10/26/2009 for the course CEM 351 taught by Professor Rathke during the Spring '08 term at Michigan State University.

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ANSWS_KEY_PROB_SET_2 - CEM 351 Fall 2008 - Prof. Rathke--...

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