310-5 - CH 310 N T Th 2-3:30 LECTURE 5 Textbook Assignment...

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Unformatted text preview: CH 310 N T Th 2-3:30 LECTURE 5 Textbook Assignment: Chapter 13 finish-Begin Chapter 15 Homework (for credit): POW 2 postedToday’s Topics: NMR interpretation-Name that Structure! Notice & Announcements: Note: Skip Chapter 14- Mass Spectrometry c b Organic Organic Lecture Series a b 1 2 c 3 a 2 Organic Organic Lecture Series b a a 2 b 3 3 Organic Organic Lecture Series b a b a 2 3 b 4 Organic Organic Lecture Series b a 3 a 1 b 5 Organic Organic Lecture Series a b a 3 b a 1 7 peaks 6 Organic Organic Lecture Series c d b a b a 1 2 d c2 3 7 Organic Organic Lecture Series a c b c 3 1 c ab 8 Organic Organic Lecture Series 9 Organic Organic Lecture Series 10 Organic Organic Lecture Series Contestants’ Hints: The molecular formula is provided. Determine index of hydrogen deficiency. Examine spectra to determine functional groups, types of protons. Write down the substructures present. Put the structure together and check the spectra for consistency. 11 Organic Organic Lecture Series C 6H 14 Unknown 1 12 Organic Organic Lecture Series Unknown 1 m is “multiplet” 3, m 4, m 13 Organic Organic Lecture Series Unknown 1 H 3C C H3 n-hexane 14 Organic Organic Lecture Series C 5 H 12 Unknown 2 15 Organic Organic Lecture Series Unknown 2 d 11 m 1 m 16 Organic Organic Lecture Series Unknown 2 d 11 m m 1 17 Organic Organic Lecture Series H 3C H 3C isopentane Unknown 2 CH3 18 Organic Organic Lecture Series C 4H 10O Unknown 3 19 Organic Organic Lecture Series Unknown 3 m is “multiplet” t 1 m 4 3 2 20 Organic Organic Lecture Series Unknown 3 3 1 2 4 21 Organic Organic Lecture Series Unknown 3 H 3C 1-butanol OH 22 Organic Organic Lecture Series C 4H 8O Unknown 4 23 Organic Organic Lecture Series Unknown 4 s 3 t 3 2 q 24 Organic Organic Lecture Series O H 3C Unknown 4 CH3 25 2-butanone Organic Organic Lecture Series C 4H 8O Unknown 5 26 Organic Organic Lecture Series Unknown 5 3, t 2 t 1 2 m 27 Organic Organic Lecture Series O C H 3C Unknown 5 H 28 n-butyraldehyde Organic Organic Lecture Series C 4H 8O Unknown 6 29 Organic Organic Lecture Series Unknown 6 6, d 1 1, septet 30 Organic Organic Lecture Series O H 3C C H CH3 Unknown 6 iso-butyraldehyde 31 Organic Organic Lecture Series C 4H 8O 2 Unknown 7 32 Organic Organic Lecture Series 3,s Unknown 7 3, t 2,q 33 Organic Organic Lecture Series O H3C C O Unknown 7 CH3 Methyl Propionate 34 Organic Organic Lecture Series C 8H 8O Unknown 8 35 Organic Organic Lecture Series 3, s Unknown 8 2 3 36 Organic Organic Lecture Series O CH3 Unknown 8 Acetophenone 37 Organic Organic Lecture Series C 8H 10 Unknown 9 38 Organic Organic Lecture Series Unknown 9 5 3 2 39 Organic Organic Lecture Series Unknown 9 CH2 CH3 Ethylbenzene 40 ...
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