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Unformatted text preview: o T c, mean = y A T c, A + y B T c, B + o P c, mean = y A P c, A + y B P c, B + o Phase Equilibrium Clapeyron Equation: Clausius Clapeyron Equation: Antoine Equation: Extensive variables: volume dependent Intensive variables: volume independent Gibbs Phase Rule: DOF = 2 + (# chemical species) (# phases)- (# reactions) vap vap V T H dT dP * = --= o vap o T T R H P P 1 1 * ln * ln C T B A P +-= * log 10 Raoults Law : y A P = P A *(T) valid where x A is close to 1 P A *(T) vapor pressure of pure liquid A at temperature T Henrys Law: P A = y A P = x A H A (T) valid where x A is close to 0 H A (T) Henrys Law constant Bubble point temperature: Temperature at which first vapor bubble forms at given pressure Dew point temperature: Temperature at which first liquid droplet forms at given pressure...
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