422-berg-jvsta-1999-1916 - Preferential sputtering effects...

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Unformatted text preview: Preferential sputtering effects in thin film processing S. Berg a) and I. V. Katardjiev Uppsala University, The Angstrom Laboratory, Department of Solid State Electronics, Box 534, 751 21 Uppsala, Sweden ~ Received 27 October 1998; accepted 23 December 1998 ! Predicting the partial sputtering yield ~ sputtered atoms of one element/incident energetic ion ! for different elements during sputtering from multielement targets is not a straightforward task. It is commonly observed that ion bombardment of composite targets exhibits preferential sputtering. Such processes are normally studied by computer simulations since theory gives qualitative results only. This work presents a systematic computational study of the major ballistically induced preferential sputtering effects taking place during ion bombardment of composite materials. It is shown that in a vast number of cases ballistic preferential sputtering is a dominant process particularly at moderate temperatures where thermodynamic effects are suppressed. In particular, sputtering from composite targets, resputtering during ion assisted deposition of composite films, sputtering of thin films onto heavy substrates, ion assisted deposition onto different substrate materials, sputter depth profiling, etc. are technological processes shown to commonly exhibit preferential sputtering. It is further shown that a number of sputtering situations exhibit along with the preferential sputtering the so called sputter yield amplification effect. The latter consists in that the partial sputtering yield of a given species is larger than the sputtering yield of the pure material. As a consequence, the sputtering yield of certain materials can be enhanced substantially by introducing small concentrations ~ a few percent ! of impurity species in the target. The work provides ample examples of various situations of academic and technological interest where preferential sputtering and sputter yield amplification occur. The major ballistic mechanisms leading to preferential sputtering and sputter yield amplification are also briefly discussed. © 1999 American Vacuum Society. @ S0734-2101 ~ 99 ! 03704-5 # I. INTRODUCTION Physical sputtering is a well known process employed in many industrial coatings applications. Sputtering can be achieved in a number of different ways, e.g., ~ i ! ion beam sputtering offers the possibility to perform sputter deposition at relatively low pressures, thereby eliminating scattering in the gas phase between sput- tered atoms and the inert sputtering gas. ~ ii ! Direct-current ~ dc !-glow discharge sputtering offers the possibility to obtain high ion current densities and consequently high sputter erosion rates....
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This note was uploaded on 12/10/2009 for the course IF PFIS1200 taught by Professor Antonio during the Spring '09 term at Universidade Federal do Rio de Janeiro.

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422-berg-jvsta-1999-1916 - Preferential sputtering effects...

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