assignment6 - CHM 3120 Assignment 6 1. Show the products of...

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1 CHM 3120 Assignment 6 1. Show the products of the following. When necessary, draw a transition state to explain the stereochemical outcome of the recation: CH 3 O a) b) Me O Me NMe 2 c) Me O OMe OSiMe 3 2. Show the products of the following synthetic transformations: Ph Me H OMe O O OH OH O O OH CH 3 C(OMe) 3 CH 3 C(OMe) 3 a) b) c) d) e)
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2 O O O H H OH H H f) g) 3. Indicate the products of the following considering both regiochemistry and stereochemistry as applicable. EtO HO OMe OH O EtO 2 C CO 2 Me CrO 3 pyridine NC O O O Ph Me O + a) b) + c) + d) e) + f) + g) +
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3 4. Show the product of the following and give a mechanism for the transformations: OH O N Cl Cl NH 2 O O Me H O Me H 1) SOCl 2 2) NaN 3 3) ∆, EtOH a) b) Br 2 , NaOH, H 2 O c) d) 1) NH 2 OH 2) H 3 PO 4 1) mCPBA 2) LiAlH 4 5. Show the product of the following transformations. O 1) H 2 NOH 2) H 2 SO 4 , H 2 O O OH mCPBA a) b) 6. A researcher is preparing a radio-labelled compound using diazomethane which has been labeled with
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assignment6 - CHM 3120 Assignment 6 1. Show the products of...

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