Assignment_7_Addition_to_carbonyls-1 - CHM 2120 Assignment...

Info iconThis preview shows pages 1–3. Sign up to view the full content.

View Full Document Right Arrow Icon
CHM 2120 – Assignment 7 In this assignment: - Oxidation of alcohols - Nucleophilic addition to carbonyls - Acetals and derivatives - Wittig reaction - Baeyer-Villiger reaction 1. Provide names for the following compounds a) c) b) d) O O O HO 2 C O 2. Draw the structure corresponding to the following names: a. ( E )-2-butenal b. 2-ethenylcyclohexanone c. 4-oxohexanal d. the benzyl carbocation e. 1-phenylethanone (acetophenone) 3. a. Give the product of the following reactions b. Explain, using a mechanism, why the product from parts i and ii are different i. OH Na 2 Cr 2 O 7 H 2 SO 4 , H 2 O ii. OH PCC CH 2 Cl 2 iii. Na 2 Cr 2 O 7 H 2 SO 4 , H 2 O OH iv. PCC OH CH 2 Cl 2
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full Document Right Arrow Icon
Assignment 7 2 4. Can Grignard reactions be conducted in protic solvents? Explain. 5. How could you synthesize the following deuterium-labeled compound from bromobenzene, magnesium, dry ether, and deuterium oxide? D 6. Give the products of the following reactions: O 1. CH 3 MgBr, Et 2 O 2. H 3 O + H H O 1. NaBH 4 , MeOH
Background image of page 2
Image of page 3
This is the end of the preview. Sign up to access the rest of the document.

{[ snackBarMessage ]}

Page1 / 7

Assignment_7_Addition_to_carbonyls-1 - CHM 2120 Assignment...

This preview shows document pages 1 - 3. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online