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Unformatted text preview: Chapter 17: Transport Phenomena Problem numbers in italics indicate that the solution is included in the Student’s Solutions Manual. Questions on Concepts Q17.1) What is the general relationship between the spatial gradient in a system property and the flux of that property? The spatial gradient of a property is a continuous difference in a physical property such as pressure, temperature, or molecular distribution. The flux of the property is a change that occurs due to the spatial gradient, defined as the amount of a given property that passes through a specific area per unit time. Q17.2) What is the expression for the diffusion coefficient, D , in terms of gas kinetic theory parameters? How is D expected to vary with an increase in molecular mass or collisional cross section? The diffusion coefficient, D , is defined as 1 3 ave D v λ = where v ave is the average speed and λ is the mean free path of a gas particle, both as defined by the kinetic gas theory. The v ave term is inversely proportional to the square root of the molar mass, therefore the diffusion coefficient will decrease as the molar mass increases. The mean free path is inversely proportional to the collisional cross section; therefore, the diffusion coefficient will decrease as the collisional cross section increases. Q17.3) Particles are confined to a plane and then allowed to diffuse. How does the number density vary with distance away from the initial plane? The number density of particles that diffuse from a fixed plane is given by the solution to Fick's Second Law of Diffusion, ( 29 2 1/2 exp 4 2 N x N Dt A Dt π  = % where N is the number of particles initially confined to the plane, D is the diffusion coefficient, A is the area of the initial plane, and t is the time. The number density in the xdirection will decrease in accord with the exponential dependence on the square of distance away from the plane (socalled Gaussian dependence). Q17.4) How does the rootmeansquare diffusion distance vary with the diffusion coefficient? How does this quantity vary with time? 171 Chapter 17/Transport Phenomena The root mean square diffusion distances depend on the square root of the both the time and the diffusion coefficient. Q17.5) What is the expression for thermal conductivity in terms of particle parameters derived from gas kinetic theory? The thermal conductivity, κ , is defined as , 1 3 v m ave A C v N N κ λ = % where C v,m is the molar volume independent heat capacity, and v ave and λ are the average speed and the mean free path, respectively. Q17.6) Why is the thermal conductivity for an ideal gas expected to be independent of pressure? Why does the thermal conductivity for an ideal gas increase as T 1/2 ?...
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This note was uploaded on 01/27/2010 for the course CHEM 3321 taught by Professor Goux during the Fall '09 term at University of Texas at Dallas, Richardson.
 Fall '09
 Goux
 Physical chemistry, pH

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