Presentation21_061122

Presentation21_061122 - Chem 6A Presentation #21 Overview...

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Chem 6A Presentation #21 2006-11-22 1 Overview Chapter 5: Liquids and Solids Intermolecular interactions
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2 Deviation from ideality: V m / V m,ideal V m V m,ideal = P V m RT V m V m,ideal V m / V m,ideal > 1 V m / V m,ideal < 1
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3 Intermolecular interactions How do the following pairs interact? Na + ................ Cl HCl ................ HCl HCl ................ Kr Kr ................ Kr
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4 Intermolecular interactions: Interaction of charged particles Na + ................ Cl E p q 1 q 2 r
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5 Intermolecular interactions: Ion–dipole interactions E p ∝ − q ion ⋅ r 2
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6 Intermolecular interactions: Dipole–dipole interactions E p ∝ − 1 ⋅ 2 r 3
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7 Intermolecular interactions: Dipole–dipole interactions
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8 Intermolecular interactions How would you explain the broken trends in this graph? Boiling point is plotted as a function of the period of the central atom.
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9 Intermolecular interactions: Hydrogen bonding interactions
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This note was uploaded on 01/31/2010 for the course CHEM CHEM 6A taught by Professor Czarkowski during the Fall '07 term at UCSD.

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Presentation21_061122 - Chem 6A Presentation #21 Overview...

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