Optional Problems_5

Optional Problems_5 - c Draw a frontier MO diagram of NO...

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Chem 103 Optional Problems #5 Heme proteins are important cellular targets for NO binding and signaling in Nature. Both Fe II and Fe III heme proteins can bind NO. a) Draw a molecular orbital diagram for NO. b) Draw the crystal field diagram of Fe II heme and fill in the electrons.
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Unformatted text preview: c) Draw a frontier MO diagram of NO binding to Fe II heme and fill with the appropriate number of electrons. d) Predict the geometry of the NO adduct and provide your reasoning. e) Repeat parts b)-d) using Fe III heme....
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