Chem 3570 materials -S10

Chem 3570 materials -S10 - 3 for R = Br Cl Nucleophiles –...

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Some Concepts and Reactions from Chem 3570 worth reviewing Functional group interconversions Alkenes – synthesis (elimination - dehydration, dehydrohalogenation, etc) and reactions Grignard and organolithium reagents - addition to carbonyl compounds Halides – Synthesis and reactions Epoxides – ring-opening reaction (addition to RMgBr, Rli and other nucleophiles) Alcohols – Synthesis and reactions (oxidation, conversion to halides (e.g.; use of PX
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Unformatted text preview: 3 for R = Br, Cl)) Nucleophiles – relative strengths, basicity, reactivity Acids and Bases – relative basicity and acidity Mechanism – arrow pushing Retrosynthesis Resonance Carbocations (formation, factors affecting stability, etc) Leaving groups – relative reactivity Lewis acids and bases Keto-enol tautomerization Stereochemistry – Retention and inversion of configuration Syn and anti-addition to C=C bonds Hydroboration-Oxidation...
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